نتایج جستجو برای: anion dependency of extraction selectivity
تعداد نتایج: 21183320 فیلتر نتایج به سال:
Extraction of relations between entities is an important part of Information Extraction on free text. Previous methods are mostly based on statistical correlation and dependency relations between entities. This paper re-examines the problem at the multiresolution layers of phrase, clause and sentence using dependency and discourse relations. Our multi-resolution framework ARE (Anchor and Relati...
Microelectrodes, made from a Cl(-)-selective liquid ion exchanger previously used to measure putative Cl- fluxes in Lilium longiflorum pollen tubes, were characterized. The electrodes were poorly selective, possessing only about 10-fold selectivity for Cl- over other anions tested. They had only 2.4-fold selectivity for Cl- over the anionic form of the H+ buffer, MES, indicating that the electr...
<scp>Chelation‐driven</scp> Regioselective 1,2‐Dearomatizations of <scp>N‐Aromatic</scp> Zwitterions
In this study, several dearomative reactions of N-aromatic zwitterions were carried out to determine the factors controlling site selectivity. A series organometallic species applied as nucleophiles for additions, which revealed that chelation between metal and nitrogen anion dominantly affected selectivity reaction in zwitterions. cascade process, involving addition followed by intermolecular ...
A ditopic receptor is shown to have an impressive ability to recognize and extract the ion pairs of various alkali halides into organic solution. X-ray diffraction analysis indicates that the salts are bound in the solid state as contact ion pairs. Transport experiments, using a supported liquid membrane and high salt concentration in the source phase, show that the ditopic receptor can transpo...
Two acyclic isophthalamide-based hosts have been synthesised and their anion binding properties have been evaluated by (1)H-NMR titrations. Different binding modes have been detected for the series of tested anions. The attachment of aminomethylpyrrole groups resulted in an improved binding selectivity. Additionally, the receptors have been incorporated as ionophores in plasticised polymeric me...
In this study, the charge selectivity of staphylococcal alpha-hemolysin (alphaHL), a bacterial pore-forming toxin, is manipulated by using cyclodextrins as noncovalent molecular adapters. Anion-selective versions of alphaHL, including the wild-type pore and various mutants, become more anion selective when beta-cyclodextrin (betaCD) is lodged within the channel lumen. By contrast, the negativel...
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