The modified NRTL (m-NRTL) model is used to represent the excess Gibbs free energy of aqueous (alcohol + electrolyte) solutions. In this work, the m-NRTL model previously developed for representation of vapor-liquid equilibria for (polymer + salt + water) systems has been extended to represent liquid-liquid equilibria of (alcohol + salt + water) systems. The proposed extension is a modified of ...

the effect of magnetic field on the liquid-liquid equilibrium of two ternary systems (water + acetic acid + butyl acetate and water + acetic acid + dimethyl succinate) at 298.15 k under atmospheric pressure was investigated. the results obtained show that the strength of the magnetic field (0.02 t) affects the solubility of acetic acid in the used organic solvents. distribution coefficients and...

the dispersive liquid–liquid microextraction (dllme) method for determination of pb +2 and cd +2 ions in the environmental water samples was combined with inductively coupled plasma-atomic emission spectrometry (icp-aes). ammonium pyrrolidine dithiocarbamate (apdc), chloroform and ethanol were used as chelating agent, extraction solvent and disperser solvent, respectively. some effective parame...

platinum extraction from different secondary sources has been experimentally tested by many researchers. in this article, dissolution of platinum in aqua-regia solution from two types of spent catalysts (reforming and nitric acid production) was kinetically studied. a variety of kinetic models for heterogeneous solid-liquid reactions, including homogeneous diffusion model, shrinking core model,...

the objective of this study was to test whether the stimuli of osmotic pressure (op), vfa or ph in the omasum would affect the passage of digesta from the rumen and feed intake in sheep. five experements were carried out. different solutions with specific, op, vfa concentration and ph were infused into the omasal body. rumen digesta volumes and outflow rates (liquid and solid) were measured by ...

Background & Aims: In this study, using a liquid-liquid microextraction method for pre-concentration trace amounts of aflatoxins, the amount of Aflatoxins B1 and B2 in powdered milk was determined. Determination of aflatoxins was done by using high-performance liquid chromatography coupled with fluorescent detector. Method: Samples were extracted by immunoaffinity column (IAC) clean-up, and the...

separation of ten sedative- hypnotic drugs was performed by rp-hplc using mixed micellar mobile phase. effect of temperature, type and amount of organic modifier in mobile phase on efficiency (n) and asymmetry factor (b/a) showed that, the appropriate conditions for a good separation were 35°c and 7% (v/v) butanol in mobile phase.  variations of selectivity factor versus butanol concentration, ...

In this paper, the sloshing response of liquid in a two dimensional rigid rectangular tank with rigid baffles is investigated using boundary element technique. A baffle is a supplementary structural element which supplies a kind of passive control on the effects of ground shaking. The complicated liquid domain is divided into two simple sub-domains so that the liquid velocity potential in each ...

A variety of alcohols readily add to 3,4-dihydro-2H-pyran under solvent free conditions in the presence of catalytic amount of acidic ionic liquid [Et3N(CH2)4SO3H][OTs] to afford the corresponding tetrahydropyranyl ethers in good to excellent yields at room temperature. The use of this procedure allows easy separation of the desired products ...

abstractbackground and objective: microwave-assisted extraction (mae) is one of the novel, fast, and efficient methods for extraction of bioactive compounds. the aim of this study was optimization of mae of betalains from red beet (beta vulgaris) and evaluating antioxidant activity of its methanolic extract.materials and methods: the effects of independent variables namely, microwave power leve...