Absorption spectra of anatase and rutile TiO2 in the 150-300 nm region before and after the deposition of Pt nanoparticles were measured. For anatase TiO2, the spectral intensity in the longer wavelength region decreased (>∼210 nm), while that in the shorter wavelength region increased (<∼210 nm). In particular, spectral band intensity in the far-ultraviolet (FUV) region (∼160 nm) was increased...

Anatase-to-rutile phase transformation was studied in milled and unmilled samples. Ball milling was carried out in two types of ball mills, planetary and tumbler, with a ball-to-powder ratio of 40:1 over 2-48 hours. First, the unmilled samples were heated in the furnace at various temperatures for different periods of time. The results revealed that the anatase-to-rutile transformation comple...

Dye-sensitized solar cell (DSSC) is a potential candidate to replace conventional silicon-based solar cells because of high efficiency, cheap cost, and lower energy consumption in comparison with silicon chip manufacture. In this report, mixed-phase (anatase and rutile nanoparticles) TiO2 photoanode was synthesized to investigate material characteristics, carriers transport, and photovoltaic pe...

Number of Papers published in peer-reviewed journals: Number of Papers published in non peer-reviewed journals: Hydrogen Photo-production from Ethanol and Water over Au/TiO2 Rutile Single Crystal Report Title This project in its final form has focused on hydrogen production from ethanol and water-ethanol mixtures over a range of different goldtitania photocatalysts. Gold supported on a commerci...

The catalytic performances of TiO2-supported Ni catalysts for the methanation CO2 have been investigated using different crystalline phases TiO2 (rutile and anatase). activity depends appreciably on nature support. rate hydrogenation decreases in order 10Ni/TiO2-rutile ≫ 10Ni/TiO2-anatase. use a mixture containing 70% 10Ni/TiO2-anatase + 30% allows significant increase reaction related to 100% ...

Highly crystallized C-doped mesoporous anatase TiO2 is prepared using a multi-walled carbon nanotube (MWCNT) mat as both a “rigid” pore template and a carbon doping source. SEM and TEM characterization shows that the MWCNT template imposed a pore structure in reverse of that of the MWCNT mat. The pore walls are formed by chain-like interconnected TiO2 nanocrystals with an average diameter about...

A new methodology was developed to synthesize uniform titania anatase nanocrystals by the hydrolysis of titanium chloride in sulfuric acid aqueous solutions at 0-90°C. The samples were characterized by Raman spectroscopy, UV-visible spectroscopy, transmission electron microscopy (TEM), electron diffraction (ED), and an Energy dispersive X-ray spectroscopy (EDS). The effects of the reaction temp...

Anatase-to-rutile phase transformation was studied in milled and unmilled samples. Ball milling was carried out in two types of ball mills, planetary and tumbler, with a ball-to-powder ratio of 40:1 over 2-48 hours. First, the unmilled samples &#10were heated in the furnace at various temperatures for different periods of time. The results revealed that the anatase-to-rutile transformation comp...

Controllable nanostructures in spin coated titanium oxide (TiO(2)) films have been achieved by a very simple means, through change of post deposition annealing temperature. Electron beam imaging and reciprocal space analysis revealed as-deposited TiO(2) films to be characterized by a dominant anatase phase which converts to the rutile form at 600 degrees C and reverts to the anatase modificatio...