Background The volatility of a compound is its ability to change into a vapor, or to evaporate at a particular temperature and pressure. The normal boiling point of a liquid usually allows comparison of its volatility to other materials, with lower boiling points indicating greater volatility, but this may be affected somewhat by the presence of other materials. Comparison of the concentration ...

A geometrically constrained phosphine bearing a tridentate NNS pincer ligand is reported. The effect of the geometric constraint on electronic structure was probed by theoretical calculations and derivatization reactions. Reactions with N−H bonds result in formation cooperative addition products. thermochemistry these transformations strongly dependent substrate, ammonia activation being thermo...

Ammonia is a gaseous material that compound composed of nitrogen and hydrogen. In this study, we analyzed the characteristics ammonia emissions at mechanically ventilation facilities gestation swine. We measured NH3 concentration, ventilation, internal temperature humidity in period from December 3, 2020 to January 17, 2021. The average concentration during measurement was 19.6 ± 3.7 ppm, inlet...

The title compound 6-amino-3-benzylmercapto-1,2,4-triazolo[3,4-f][1,2,4]-triazin-8(7H)-one (4), molecular formula C(11)H(10)N(6)OS, was obtained by the reaction of 3-amino-2-benzyl-6-hydrazino-1,2,4-triazin-5(2H)-one (3) with carbon disulfide in a water/pyridine mixture. Compound 4 can also be synthesized by reacting 6-amino-3(2H)mercapto-1,2,4-triazolo[3,4-f][1,2,4]triazin-8(7H)-one (7) with b...

OBJECTIVE This paper presents the results of a clinical study assessing the in vivo effects on plaque metabolism of a new dentifrice containing 1.5% arginine, an insoluble calcium compound, and 1450 ppm fluoride compared to a commercially available dentifrice containing 1450 ppm fluoride alone. METHODS A four-week, parallel, randomized, double-blind clinical study using 54 subjects was conduc...

The crystal structure of the title compound, [Rb(C(12)H(24)O(6))](3)[Sb(7)]·4NH(3), fills the gap between the already known Zintl anion ammoniates {[Cs(18-crown-6)](3)Sb(7)}(2)·9NH(3) [Wiesler (2007 ▶). Dissertation, Universität Regensburg, Germany] and [K(18-crown-6)](3)Sb(7)·4NH(3) [Hanauer (2007 ▶). Dissertation, Universität Regensburg, Germany]. As in the two known compounds, the anti-mony ...

The discovery three years ago of thefirst well-defined complex compound containing the nitrogen molecule a complex of ruthenium aroused great interest in such compounds and in their relation to nitrogen fixation. Since then a number of other nitrogen complexes have been obtained, but as yet, despite reports to the contrary, attempts to reduce their nitrogen to ammonia have been unsuccessful. In...

Phenylalanine ammonia-lyase (PAL) performs a major role in the biosynthesis of polyphenolic compounds, which are involved in the defense mechanism in harsh environments related to different stimuli. The present study was carried out to detect the activity of phenylalanine ammonia-lyase in different plant parts of Anacardium occidentale such as flower, young leaves, shoot tip, mature leaves, raw...

The title compound, Rb2O2·2NH3, has been obtained as a reaction product of rubidium metal dissolved in liquid ammonia and glucuronic acid. As a result of the low-temperature crystallization, a disolvate was formed. To our knowledge, only one other solvate of an alkali metal peroxide is known: Na2O2·8H2O has been reported by Grehl et al. [Acta Cryst. (1995), C51, 1038-1040]. We determined the pe...