نتایج جستجو برای: amine compounds
تعداد نتایج: 244534 فیلتر نتایج به سال:
Treatment of 1-(5-bromo-2-chloro-6-methylpyrimidin-4-yl)-1-methylhydrazine withdimethylthiocarbamoylchloride gave 7-chloro-N,N, 1,5-tetramethyl-1H-pyrimido[4,5-e][1,3,4]thiadiazin-3-amine in basic acetonitrile. The latter compounds were reacted withsecondary amines in boiling ethanol to afford the related 7-amino derivatives.
Selective nucleophilic substitution on a perfluorophenyl unit comprising a BODIPY fluorophore using an alkanethiol or a primary amine offers a quantitative fluorophore labelling strategy, while retaining high photostability and emission quantum yields approaching unity.
The title com plexes have been obtained and shown by elem ental analysis, IR and PMR spectra to be octahedral. The trans structure has been assigned to bis(/?-acylvinyl)amine com plexes based on m agnetic equivalence of geminal m ethyl groups in appropriately substituted representatives of this group of compounds. The (8 -quinolyl-/?-acylvinyl)amine com plexes m ay have either trans or s -cis (...
A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions--'epoxy-amine' and 'thiol-ene' coupling--for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.
Nitroso compounds have two reactive nitrogen and oxygen atoms. It is interesting and important to perform a nitrogen or oxygen selective reaction with interesting substrates. These atom specific reactions are crucial to specifically synthesis of specific compounds. An enantioselective N-specific reaction of nitrosobenzene with unmodified aldehydes was successfully achieved catalyzed first by a ...
The synthesis of the complex spiro{pyrrolidine-3,1′-pyrrolo[3,4-c]pyrrole} skeleton under mild conditions is presented. order addition a primary amine, two equivalents corresponding maleimide and, finally, aldehyde paramount importance to obtain these final compounds in very high yields. mechanism was studied by performing simple tests, Michael type amine onto being key step. Interestingly, hyb...
Fermented African oil bean (Pentaclethra macrophylla Benth) seed is a successful and well studied seasoning and snack in parts of Western Africa. GC-MS analysis of fermenting seeds revealed a mixture of several volatile aroma compounds which changed with time and starter organism. During natural mixed culture process 36 volatile compounds including 12 hydrocarbons, 10 esters, 5 alcohols, 2 phen...
Monoliths functionalized with ethylene diamine-derived ligands were synthetized within micro-sized channels as highly permeable catalytic supports for the immobilization of in-situ generated gold nanoparticles. The as-obtained hybrids, essentially differing on grafted amine-containing compared, notably regarding immobilized nanoparticles morphology and their dispersion at monolith pore surface....
inhibitory effect of three benzothiazole derivatives (1, 3-benzothiazol-2-amine (bta), 6-methyl-1, 3-benzothiazol-2-amine (mbta) and 2-amino-1, 3-benzothiazole-6-thiol (tbta)) on corrosion of carbon steel has been studied using density functional theory (dft) method in gas and aqueous phases. quantum chemical parameters such as ehomo (highest occupied molecular orbital energy), elumo (lowest un...
Borane amine compounds hold promise in a chemical hydrogen storage setting due to their high gravimetric and volumetric content of releasable hydrogen. The heats of formation and the thermodynamics of the dehydrogenation of N-methyl substituted cyclodi-, cyclotriand cyclotetraborazane were predicted at the G3(MP2) level following B3LYP/DGDVZP2 level optimization. The dehydrogenation of the N-me...
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