A polyethylenimine-impregnated hierarchical silica monolith exhibited significantly higher CO(2) capturing capacity than other silica-supported amine sorbents, and produced a reversible and durable sorption performance.

The potential of solid phase extraction (SPE) clean-up has been assessed to reduce matrix effects (signal suppression or enhancement) in the liquid chromatography-tandem mass spectrometry (LC-MS/MS) analysis of lipophilic marine toxins. A large array of ion-exchange, silica-based, and mixed-function SPE sorbents was tested. Polymeric sorbents were found to retain most of the toxins. Optimizatio...

Looking for new green and environmentally friendly bio sorbents metal removal from polluted wastewater, the present study investigates potential sorbent Cd(II) wastewater namely, mechanism uptake capacity of by brown algae, Fucus vesiculosus Irish Sea. This work takes a comprehensive approach involving combination qualitative quantitative information collected macro to atomistic scale, in direc...

A brief review of charge-transfer (CT-) thromatography is presented. Hydrophilic gels such as Sephadex exhibit weak electron acceptor and donor prOperties due to the presence of matrix hydroxyls or matrix-bound water. Stronger O-adsorbents for chromatography in aqueous solutions are obtained by introduction of electron acceptor or donor substituents. The adsorption properties of such gels are d...

Affinity sorbents and detoxification strategies are described to remove different amounts of endotoxin. Advantages and disadvantages of the employed ligands are discussed and it is shown that both electrostatic and hydrophobic interactions contribute to the association of ligands and endotoxins. Furthermore, the flexibility of the ligand is more important than an exact structural match between ...

Sample preparation has been recognized as a major step in the chemical analysis workflow. As such, substantial efforts have been made in recent years to simplify the overall sample preparation process. Major focusses of these efforts have included miniaturization of the extraction device; minimizing/eliminating toxic and hazardous organic solvent consumption; eliminating sample pre-treatment an...

introduction one of the important events that usually occur in seas and large water bodies’ concurrent with the change of season is the growth and species increase of phytoplankton. in the natural environment, this event does not result in imbalances of water ecosystems. however, pollution caused by human activities results in excessive growth and reproduction of phytoplankton and other opportu...

pollutions. Recently, both Persian Gulf and Gulf of Oman are experiencing several types of pollution including oil spills and heavy metal pollutions as well as Harmful Algal Bloom (HAB) caused by biological and environmental changes. Theiroccurrence of the red tide or harmful algal bloom during fall and winter 2008-2009 caused numerous unknown factors in the Strait of Hormuz, Persian Gulf and G...

Hybrid sorbents and biosorbents were synthesized via chemical and biological treatment of active carbon by simple and direct redox reaction followed by surface loading of baker's yeast. Surface functionality and morphology of chemically and biologically modified sorbents and biosorbents were studied by Fourier Transform Infrared analysis and scanning electron microscope imaging. Hybrid carbonac...

Recent revision of the arsenic in drinking water standard will cause many utilities to implement removal technologies. Most of the affected utilities are expected to use adsorption onto solid media for arsenic removal. The arsenic-bearing solid residuals (ABSR) from adsorption processes are to be disposed of in nonhazardous landfills. The Toxicity Characteristic Leaching Procedure (TCLP) tests ...