The possibility of modeling the cooling processes Bi2GeO5 metastable compound using ProCAST software package is shown. Despite a number assumptions used in simulation, calculation results showed good convergence with real rates melts and can be useful for development Bi2O3 – GeO2 system order to obtain materials given set properties character microstructure.

We report the facile and efficient synthesis of common electrophilic haloboranes via a protonolysis reaction between Piers’ borane, HB(C6F5)2, H−X (X=Cl, Br). This route benefits from fast times, easy setup, minimal workup to yield analytically pure etherates, (C6F5)2BCl(OEt2) (1) (C6F5)2BBr(OEt2) (2), as well ether-free tri-coordinate species, (C6F5)2BBr (3).

Abstract C 8 H 4 INS 3 , monoclinic, P 2 1 / c (no. 14), a = 11.8060(19) Å, b 7.8961(14) 11.972(2) β 110.981 ( 2 ) ° $110.981(2){}^{\circ}$ V 1042.1(3) Å Z 4, R gt ( F ) 0.0279, wR ref 0.0739, T 296(2) K.