The toxic arsenate ion can behave as a phosphate analog, and this can result in arsenate toxicity especially in areas with elevated arsenate to phosphate ratios like the surface waters of the ocean gyres. In these systems, cellular arsenate resistance strategies would allow phytoplankton to ameliorate the effects of arsenate transport into the cell. Despite the potential coupling between arsena...

In the title compound, tris-odium dicobalt arsenate diarsenate, Na₃Co₂AsO₄As₂O₇, the two Co atoms, one of the two As and three of the seven O atoms lie on special positions, with site symmetries 2 and m for the Co, m for the As, and 2 and twice m for the O atoms. The two Na atoms are disordered over two general and special positions [occupancies 0.72 (3):0.28 (3) and 0.940 (6):0.060 (6), respec...

red mud (rm), a waste tailing from alumina production, (as an important environmental problem), can be used as a strong absorbent pollutant. in this study, the modified red mud (mrm) and pillared clay (pilc) were used for the removal of arsenate from water. the modified red mud (mrm) and pilc complex were characterized using xrd, sem and xrf microanalysis. the adsorption of arsenate on modified...

The kinetic parameters for inorganic phosphate and inorganic arsenate as substrates for the synthesis of ATP and ADP-arsenate, respectively, by beef heart submitochondrial particles have been determined. The Vm and Km values for arsenate and phosphate, as well as the Km values for ADP in the two reactions, are the same within experimental error of the measurements. These data are consistent wit...

ARSENIC poisoning in livestock may be caused by arsenic trioxide (white arsenic), paris green, sodium arsenite, and sodium arsenate. Arsenic has been a common cause of accidental and criminal poisoning of animals because it often is used to kill insects, parasites, weeds, and rodents and as a tonic for animals. Arsenic compounds usually are palatable to animals, especially when they are hungry ...

Kumar et al. (2015)'s review on arsenic (As) detoxification in plants and related biotechnology provides current updates about the As metabolism and recent developments in engineering As-tolerant and low-As plants. Although we agree with most of the viewpoints expressed in the review, we would like to clarify the naming and functions of ACR2, arsenate reductase, and ACR3 arsenite efflux transpo...

The hydrolysis of sodium borohydride as a source of hydrogen gas is studied at different mole ratios of H+ to NaBH4. The sulfonated porous carbon (SPC) is used as a source of hydrogen ion and catalyst. It is found that the sulfonated porous carbon exhibits high activity for the hydrolysis of NaBH4 to generate hydrogen gas at room temperature in comparison to Amberlyst-15 and Nafion-NR50. The ki...

Terms and conditions of current drinking water quality standards, including reducing the maximum arsenic concentration from 50 μgl-1 to 10 μgl-1 and predicted stricter standards in future, reveals the necessity for development of new technologies. This study aimed to prepare and evaluate a new nanocomposite membrane using graphene oxide (GO) thin layer to remove arsenic (v) from water. To fabri...

Chromosome analysis of lymphocytes from patients who had been exposed to arsenic showed frequent structural and numerical aberrations, even with an interval of decades since the last exposure. The in vitro addition of sodium arsenate induced the same chromosome changes--even to extreme of chromosome pulverizations--upon lymphocyte cultures from healthy subjects. Radioactive incorporation studie...

The structure of the title compound tris-odium aluminium bis-(arsenate), Na(3)Al(AsO(4))(2), is built up from AlO(4) and AsO(4) corner-sharing tetra-hedra, forming an undulating two-dimensional framework parallel to (100). The layers are constituted of large Al(6)As(6)O(36) rings made up from six AlO(4) and AsO(4) tetra-hedra in which two sodium cations are situated, the third sodium cation bei...