The frictional behaviors of fullerenes C60 and C70 were studied because they were speculated to be solid lubricants. For the sublimated pure C60 films on Si(001), a high friction coefficient (0.55–0.8) was observed under different loads and pin materials. For the C70 film, the friction coefficient showed a pin dependence, which changed from 0.5 with an Al2O3 pin to about 0.9 with a 440 stainles...

To model the active layer in the hetero-junction solar cells, the C60, C70, PC60BM, PCBDAN fullerenes as acceptor, and (OS)n=1) oligoselenophenes as donor were considered. The (OS)n=14/C60, (OS)n=14/C70, (OS)n=14/PC60BM, and (OS)n=14/PCBDAN blends as a model of the active layer in the BHJ solar cell were chosen, and the optoelectronic properties were studied. The calculated efficiency of these ...

The interactions between C60 and transition metal elements have attracted much attention for their possible formation of new functional materials, and it has been shown that the interesting structures are evolved in the atomistically mixed thin films of C60 and transition metals with the poor or the negligible solubility with carbons. However, the detailed studies of the microstructures have be...

We have investigated the adsorption of some amino acids and an oligopeptide by fullerene (C60) and fullerene nanowhiskers (FNWs). C60 and FNWs hardly adsorbed amino acids. Most of the amino acids used have a hydrophobic side chain. Ala and Val, with an alkyl chain, were not adsorbed by the C60 or FNWs. Trp, Phe and Pro, with a cyclic structure, were not adsorbed by them either. The aromatic gro...

Inter-Coulombic decay (ICD) resonances in the photoionization of Cl@C60 endofullerene molecule are calculated using a perturbative density functional theory (DFT) method. This is first ICD study an open shell atom fullerene cage. Three classes probed: (i) Cl inner vacancies decaying through C60 outer continua, (ii) and (iii) either system continua Cl-C60 hybrid levels, Auger-ICD resonances. Com...

We theoretically studied the electronic and electrical properties of metallic and semiconducting peapods with encapsulated C60 (C60@CNT) as a function of the carbon nanotube (CNT) diameter. For exothermic peapods (CNT diameter > 11.8 Å), only minor changes, ascribed to a small structural deformation of the nanotube walls, were observed. These include a small electron charge transfer (less than ...

Eisenia fetida was used as a model terrestrial organism to assess the potential ecotoxicity of molecular pristine C60 in soil. Reproduction (assessed by counting cocoon numbers) was hindered only at very high C60 concentrations (5% by weight), and C60 (up to 1%) was not avoided and did not hinder earthworm growth. This suggests that E. fetida is unlikely to experience acute toxicity as a result...

We report on the synthesis of well-defined thermoresponsive water-soluble diblock copolymer and homopolymers functionalized with controlled numbers of C60 moieties at predetermined positions via the combination of atom transfer radical polymerization (ATRP) and click chemistry. Azide-containing polymer precursors including monoazide-terminated and R,R-diazide-terminated poly(N-isopropylacrylami...

Partition and localization of C60 and its derivative C60(OH)18-22 in lipid membranes and their impact on mitochondrial activity were studied, attempting to correlate those events with fullerene characteristics (size, surface chemistry, and surface charge). Fluorescence quenching studies suggested that C60(OH)18-22 preferentially populated the outer regions of the bilayer, whereas C60 preferred ...

The chlorination of singly and multiply charged C60 cations has been investigated with the selected-ion flow tube technique. Observations are reported for the reactions of C60 , C60 21 and C60 z31 with Cl2, CCl4, CDCl3, CH2Cl2 and CH3Cl at room temperature (295 6 2 K) in helium at a total pressure of 0.35 6 0.02 Torr. C60 z1 and C60 21 were observed not to chlorinate, or react in any other way,...