The surface crystal structure of the Co3O4(1 1 0) spinel was characterized by low energy electron diffraction (LEED), X-ray photoelectron spectroscopy (XPS), and Auger electron spectroscopy (AES). Well-defi ned LEED diffraction patterns showed an unreconstructed Co3O4(1 1 0) surface in Type A termination, and XPS and Auger indicated the surface to be stoichiometric with octahedral and tetrahedr...

To solve the reduced output voltage caused by the high lithium redox potential of Co3O4 when applied as an anode material in full cells, an effective strategy is to partially replace Co by Mn to form MnCo2O4 without changing the original crystal structure. Herein, 3D hierarchical MnCo2O4 nanosheets arrays grown via a hydrothermal method on carbon cloths, as binder-free anodes for lithium-ion ba...

High activity of a catalyst and its thermal stability over lifetime are essential for catalytic applications, including gas sensors. Highly porous materials attractive to support metal catalysts because they can carry large quantity well-dispersed nanoparticles, which well-accessible reactants. The present work investigates the long-term mesoporous Co3O4-supported Au–Pd (Au–Pd@meso-Co3O4), with...

A novel one-step hydrothermal and calcination strategy was developed to synthesize the unique 1D oriented Co3O4 crystal nanofibers with (220) facets on the carbon matrix derived from the natural, abundant and low cost wool fibers acting as both carbon precursor and template reagent. The resultant W2@Co3O4 nanocomposite exhibited very high specific capacity and favorable high-rate capability whe...

A simple and scalable coordination-derived method for the synthesis of porous Co3O4 hollow nanospheres is described here. The initially formed coordination-driven self-assembled aggregates (CDSAAs) could act as the precursor followed by calcination treatment. Then the porous hollow Co3O4 nanospheres are obtained, in which the primary Co3O4 nanoparticles are inter-dispersed. When the nanospheres...

High oxygen evolution overpotential and inexpensive Ti/Co3O4/PbO2/(SnO2+Sb2O3) and (Ti/(SnO2+Sb2O3) electrodes were investigated in this work. These electrodes were prepared and used as anodes for removal of Reactive Black 5 (RB5) dye in aqueous solution. In some local cases in Palestine, wastewater color was found to be the only problem in meeting local effluent standards. This investigation r...

We prepared 0.1 wt%-30 wt% Pd-loaded Co3O4 by a colloidal mixing method and investigated the sensing properties of a Pd-loaded Co3O4 sensor element, such as the sensor response, 90% response time, 90% recovery time, and signal-to-noise (S/N) ratio, toward low nitric oxide (NO) gas levels in the range from 50 to 200 parts per billion. The structural properties of the Pd-loaded Co3O4 powder were ...

We report directly grown strongly adherent graphene on Co3O4(111) by carbon molecular beam epitaxy (C MBE) at 850 K and density functional theory (DFT) findings that the first graphene layer is reconstructed to fit the Co3O4 surface, while subsequent layers retain normal graphene structure. This adherence to the Co3O4 structure results from partial bonding of half the carbons to top oxygens of ...

Mesostructured Co3O4/C composites of high surface area have been synthesized via a one-step replica route by co-nanocasting cobalt and carbon precursors into mesoporous silica, in which the Co3O4 nanoparticles are homogeneously dispersed in the mesoporous structure of carbon substrates. The mesostructured composites showed relatively high catalytic activities for oxygen reduction reaction (ORR)...

Double-shell cobalt monoxide (CoO) hollow particles were successfully synthesized by a facile and effective one-pot solution-based synthetic route. The inner architecture and outer structure of the double-shell CoO hollow particles could be readily created through controlling experimental parameters. A possible formation mechanism was proposed based on the experimental results. The current synt...