A questão ambiental tem sido motivo de ampla discussão em nível nacional e internacional, face à exploração desenfreada dos recursos naturais enorme geração resíduos por parte da indústria. reciclagem sólidos é uma das formas atenuar o proble- ma, reduzindo, conseguinte, impacto ambiental. Esta pesquisa objetivou caracterizar a escória ferro-cromo como agregado graúdo para produção concreto. Os...

In magnetism, of which molecular magnetism is a part, the term frustration is used rather sloppily. Sometimes one gains the impression that if the reason for some phenomenon is not quite clear then it is attributed to frustration. In this paper a discussion of the effects of frustration that are relevant for the field of molecular magnetism is presented. As will become clear later these effects...

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Resonance Raman spectra of horseradish peroxidase (HRP) in the 200 to 600 cm" region were measured for the reduced and oxidized states and in the presence and absence of substrate, For the reconstituted HRP with a S4Fe-substituted heme, the Raman line of ferro HRP at 244 cm" was shifted to 246 cm" but all other modes remained unshifted. The amount of the frequency shift agreed with that observe...

Uma ferro porfirina poli-clorada, Fe(PCl 8 )Cl, foi sintetizada e usada como catalisador em reações de oxidação de hidrocarbonetos por iodosilbenzeno e peróxido de hidrogênio, em solução e ancorado covalentemente na aminopropilsilica. Embora a Fe(PCl 8 )Cl tenha mostrado a mesma eficiência da ferro porfirina precursora, Fe(P)Cl, na epoxidação de alcenos, foi um catalisador mais eficiente na hid...

The exchange bias (EB) effect was discovered 60 years ago by Meiklejohn and Bean. Meanwhile the EB effect has become an integral part of modern magnetism with implications for basic research and for numerous device applications. The EB effect was the first of its kind which relates to an interface effect between two different classes of materials, here between a ferromagnet and an antiferromagn...

Highly stoichiometric zinc ferrous ferrites Zn,F+,O, were prepared and characterized by magnetization, desacwmmodation, electrical conductivity, thermal expansion and magnetostriction measurements. The results of the magnetization measurements indicate that up till x = 0.5 the magnetic structure is collinear, which led to the highest saturation magnetizations ever found in spinel femtes. The th...

The critical properties of the mixed ferro/antiferromagnetic q-state Potts model on the square lattice are investigated using the numerical transfer matrix technique. The transition temperature is found to be substantially lower than previously found for q = 3. It is conjectured that there is no transition for q > 3, in contradiction with previous results.

Results of computer simulations based on ab initio methods are presented for the newly observed magnetism found in carbon-based and non-traditional inorganic materials. These results reinforce our previously proposed explanation about the nature and the origin of this “new type of magnetism” which attributes this to electron correlations effects which develop in the presence of defects and dopi...

Abstract At the core of theoretical framework ferroelectric field-effect transistor (FeFET) is thermodynamic principle that one can determine equilibrium behavior (FERRO) systems using appropriate potential. In literature, it often implicitly assumed, without formal justification, Gibbs free energy potential and impact charge accumulation be neglected. this Article, we first formally demonstrat...