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Silicon has been widely considered as the next generation anode material for lithium-ion batteries, due to its substantially higher capacity compared to conventionally used graphite. However, silicon-based electrodes suffer from problems such as poor capacity retention and low coulombic efficiency. Significant amount of work has been devoted to improve the performance of silicon electrodes. Amo...
A graphite powder disk sandwiched between two nickel screens was used as a lithium-insertion working electrode. Electrochemical impedance spectroscopy (EIS), galvanostatic intermittent titration (GIT) using pulsed microcurrent, and in-situ intrinsic resistance measurements were used for the evaluation of kinetics and intrinsic (i.e. physical) resistance changes during charge–discharge cycling f...
Application of a functional surface coating on Li-ion battery electrodes can potentially result in a significant enhancement of the lifespan of the battery cell. In particular, atomic layer deposition (ALD), which can create highly conformal ultrathin oxide films on many different electrodes has been shown to increase the cyclability in these systems. In this study, we explore the impact of suc...
The cycling performance and SEI composition of Si nano-particle anodes in electrolytes containing 5–25 wt% fluoroethyelene carbonate (FEC) and 3–6 wt% vinylene carbonate (VC) has been investigated by a combination of by electrochemical cycling, electrochemical impedance spectroscopy, IR-ATR and XPS. The incorporation of FEC or VC changes the cycling performance, impedance, electrode morphology,...
In all 278 members of British Mensa completed three questionnaires concerned with self-estimated intelligence (SEI), Beliefs about Intelligence and its measurement and a gender role inventory. Males rated their domain masculine intelligence (a combination of mathematical, spatial and verbal intelligence) almost three (143.9) and females more than two (134.3) standard deviations above the mean a...
Seismic screening, evaluation, and rehabilitation design of two existing wood-framed structures are performed using FEMA 154, FEMA 356, ASCE/SEI 31, and the 1997 UBC. FEMA 154 screening demonstrates the importance of examining construction drawings. Plans revealed a structural deficiency, but screening alone indicated no further evaluation is needed. Demand-to-capacity ratios for shear walls an...
BACKGROUND Sei-1 is an oncogene capable of inducing double minute chromosomes (DMs) formation. DMs are hallmarks of amplification and contribute to oncogenesis. However, the mechanism of Sei-1 inducing DMs formation remains unelucidated. RESULTS DMs formation significantly increased during serial passage in vivo and gradually decreased following culture in vitro. micro nuclei (MN) was found t...
Since the potential for alloying lithium with silicon is outside the window of stability of common commercial electrolytes, silicon surfaces form an amorphous solid electrolyte interphase (SEI) under applied potential, which hampers silicon's performance as a lithium-ion battery anode. We have investigated the composition, distribution, and ambient stability of the SEI formed on undoped silicon...
Electrochemical impedance spectroscopy (EIS) and in-situ intrinsic resistance measurements were applied to sandwiched disk graphite electrodes to investigate the mechanism of formation of irreversible capacity during initial galvanostatic or potentiostatic lithium intercalation into graphite in four different electrolyte formulations. The stability of the solid electrolyte interphase (SEI) film...
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