Shewanella loihica strain PV-4 harbors both a functional denitrification (NO3 (-)→N2) and a respiratory ammonification (NO3 (-)→NH4 (+)) pathway. Batch and chemostat experiments revealed that NO2 (-) affects pathway selection and the formation of reduced products. Strain PV-4 cells grown with NO2 (-) as the sole electron acceptor produced exclusively NH4 (+). With NO3 (-) as the electron accept...

[1] We present an approach to infer ground-level nitrogen dioxide (NO2) concentrations by applying local scaling factors from a global three-dimensional model (GEOS-Chem) to tropospheric NO2 columns retrieved from the Ozone Monitoring Instrument (OMI) onboard the Aura satellite. Seasonal mean OMI surface NO2 derived from the standard tropospheric NO2 data product (Version 1.0.5, Collection 3) v...

We investigate the effects of aerosol optical depth (AOD), single scattering albedo (SSA), aerosol peak height (APH), measurement geometry (solar zenith angle (SZA) and viewing zenith angle (VZA)), relative azimuth angle, and surface reflectance on the accuracy of NO2 slant column density using synthetic radiance. High AOD and APH are found to decrease NO2 SCD retrieval accuracy. In moderately ...

Surface NO2 volume mixing ratio (VMR) at a specific time (13:45 Local time) (NO2 VMRST) and monthly mean surface NO2 VMR (NO2 VMRM) are estimated for the first time using three regression models with Ozone Monitoring Instrument (OMI) data in four metropolitan cities in South Korea: Seoul, Gyeonggi, Daejeon, and Gwangju. Relationships between the surface NO2 VMR obtained from in situ measurement...

Nitric oxide (NO) in oxygen-containing aqueous solution has a short half-life that is often attributed to a rapid oxidation to both NO2- and NO3-. The chemical fate of NO in aqueous solution is often assumed to be the same as that in air, where NO is oxidized to NO2 followed by dimerization to N2O4. Water then reacts with N2O4 to form both NO2- and NO3-. We report here that NO in aqueous soluti...

Extensive studies have been conducted in the past decades to predict the environmental abiotic and biotic redox fate of nitroaromatic and nitramine explosives. However, surprisingly little information is available on one-electron standard reduction potentials (Eo(R-NO2/R-NO2-)). The Eo(R-NO2/R-NO2-) is an essential thermodynamic parameter for predicting the rate and extent of reductive transfor...

Four novel phosphine-substituted ruthenium(ii) polypyridine complexes with nitrogen oxides-trans(P,NO2)-[Ru(trpy)(Pqn)(NO2)]PF6 (trans-NO2), cis(P,NO2)-[Ru(trpy)(Pqn)(NO2)]PF6 (cis-NO2), [Ru(trpy)(dppbz)(NO2)]PF6 (PP-NO2), and cis(P,NO)-[Ru(trpy)(Pqn)(NO)](PF6)3 (cis-NO)-were synthesised (trpy = 2,2':6',2''-terpyridine, Pqn = 8-(diphenylphosphanyl)quinoline, and dppbz = 1,2-bis(diphenylphosphan...

the effects of different concentrations of cdcl2 and alcl3 on nh4+ and no2? oxidation in an aqueous system were investigated. alcl3 had no effect on nh4+ removal and its oxidation to no2?, whereas no2? disappearance was greatly enhanced by alcl3. in contrast, cdcl2 delayed removal of nh4+ and its subsequent oxidation to no2? and also decreased the rate of no2? disappearance. when compared to th...

In a prospective study of infants' exposure to nitrogen dioxide (NO2)* and respiratory illness, NO2 concentrations were measured in more than 1,400 homes in Albequerque, NM, From January 1988 through June 1991 (Health Effects Institute Research Report Number 58, Parts I, II and III). This report characterizes the variability in indoor NO2 concentrations across seasons and years, and identifies ...