Rhenium nanocrystalline particles (Re NPs), of 2 nm size, were prepared from NH4ReO4 under mild conditions in neat alcohol. The unsupported Re NPs convert secondary and benzylic alcohols to ketones and aldehydes, respectively, through catalytic acceptorless dehydrogenation (AD). The oxidant- and acceptor-free neat dehydrogenation of alcohols to obtain dihydrogen gas is a green and atom-economic...

This study investigated the suspension of poly(ε-caprolactone) nanoparticles as an ocular delivery system for flurbiprofen (FB-PεCL-NPs) in order to overcome the associated problems, such as stability, sterility, tolerance, and efficacy, with two different FB-PεCL-NP formulations. The formulations were stabilized with poloxamer 188 (1.66% and 3.5%) and submitted individually for freeze-drying a...

Currently, impacts of exposure to TiO2 nanoparticles (NPs) on the cardiovascular system are not well understood. The aim of this study was to investigate whether TiO2 NPs induce myocarditis and its underlying molecular mechanism in the cardiac inflammation in mice. Mice were exposed to TiO2 NPs for 6 months; biochemical parameters of serum and expression of Th1-related and Th2-related cytokines...

in this scientific research, for the first time, the removal of radioactive strontium-90 (90sr) by γ-mno2-aga zeolite as a novel nanocomposite adsorbent was accomplished under different conditions such as ph, temperature, adsorbent amount and the contact time that are examined from drinking water of ramsar city and monitored via ultra low-level liquid scintillation counting (lsc) technique. pri...

Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Ya Chen Name of the doctoral dissertation Silver nanoparticles embedded in glass by ion exchange method for biosensor applications Publisher School of Electrical Engineering Unit Department of Microand Nanosciences Series Aalto University publication series DOCTORAL DISSERTATIONS 125/2012 Field of research Photonics Manuscript...

While zinc oxide (ZnO) nanoparticles (NPs) have been recognized to have promising applications in biomedicine, their immunotoxicity has been inconsistent and even contradictory. To address this issue, we investigated whether ZnO NPs with different size (20 or 100 nm) and electrostatic charge (positive or negative) would cause immunotoxicity in vitro and in vivo, and explored their underlying mo...

With a large specific surface area, high reactivity, and excellent adsorption properties, nano zerovalent iron (nZVI) can degrade a wide variety of contaminants in wastewater. However, aggregation, oxidation, and separation issues greatly impede its wide application. In this study, MoS₂/Fe₃O₄/nZVI nanocomposites were successfully synthesized by a facile step-by-step approach to overcome these p...

Experiments were performed in parallel using six identical UASB (upflow anaerobic sludge blanket) reactors to examine the effects of iron (Fe2+) on sludge granulation during start-up. Introduction of Fe2+ at concentrations of 300 and 450 mg/L enhanced the granulation process in UASB reactors, while dosage of Fe2+ (150 mg/L) had little effect on the sludge granulation. The Fe2+concentration in g...

in this paper, grafting of acrylic acid monomer on gum tragacanth was performed. variable of experiment included concentration of initiators and monomer, time, and temperature. grafting efficiency was measured in the term of percentage of grafting (%g) and percentage of grafting efficiency (%e). effectiveness of grafted gum in ferrous ion removal at different condition was assessed. according t...

Liquid drops on deformable soft substrates exhibit quite complicated wetting behavior as compared to those rigid solid substrates. We report a of Co nanoparticles (NPs) sapphire substrate during pulsed laser-induced dewetting (PLID). NPs produced by PLID wetted the with contact angle near 70°, which is in contrast typical metal thin films exhibiting angles greater than 90°. In addition, nanosca...