By coupling two different magnetic materials inside a single composite nanoparticle, the shape of the magnetic hysteresis can be engineered to meet the requirements of specific applications. Sandwich-like composite nanoparticles composed of a hard-magnetic Ba-hexaferrite (BaFe12O19) platelet core in between two soft-magnetic spinel iron oxide maghemite (γ-Fe2O3) layers were synthesized using a ...

The changes of the phase composition of iron oxide samples prepared by solgel method using single precursor both for nanoparticles and the matrix were studied by x-ray diffraction. Obtained data were analyzed by an approach using the Debye formula which is suitable for the size of particles up to about 10 nm. The phase composition of the nanoparticles was described by a core-shell model corresp...

Ni2+ supported on hydroxyapatite-core@shell γ-Fe2O3 nanoparticles (γ-Fe2O3@HAp-Ni2+) was found to be a useful catalyst for the synthesis of benzimidazole derivatives from o-phenylenediamine and aldehydes under solvent and solvent-free conditions at 80 °C. This reaction affords the corresponding benzimidazole derivatives compared with the classical reactions this method consistently gives a high...

A mild, green and highly efficient route for regio-selective amination of oxiranes was developed via incorporation of Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) cations onto the surface of hydroxyapatite-encapsulated γ-Fe2O3 nanoparticles (γ-Fe2O3@HAp). Among six magnetically recoverable catalytic systems denoted as [γ-Fe2O3@HAp-MII], the catalyst in which M designated as Fe(II) showed t...

This study was supported by EU FP7 grant GlowBrain (REGPOT–2012–CT2012– 316120) to S.G. and by a University of Trento Startup Grant and the Cassa di Risparmio di Trento e Rovereto Grant n. 2011.0251 to S.C. Since the central nervous system shows very little capability for self-repair following ischemic injury, regenerative medicine approaches are increasingly interested in the use of neural ste...

A new immobilized palladium-pyridine complex on γ-Fe2O3 magnetic nanoparticles was synthesized and characterized by SEM, TEM, TGA, ICP, XPS, XRD, FT-IR and CHN analysis. The catalytic activity of synthesized catalyst has been investigated in Heck, Suzuki and Sonogashira coupling reactions using a series of aryl halides. The catalyst was easily isolated from the reaction mixture by an external m...

Nanoscale objects that combine high luminescence output with a magnetic response may be useful for probing local environments or manipulating objects on small scales. Ideally, these two properties would not interfere with each other. In this paper, we show that a fluorescent polymer host material can be doped with high concentrations of 20-30 nm diameter magnetic γ-Fe2O3 particles and then form...

magnetic nanoparticles are the good choice for using in mri as the contrast agent. iron oxide particles such as magnetite (fe3o4) or its oxidized form maghemite (γ-fe2o3) are the most commonly employed in biomedical applications. in this study, we synthesized and optimized the preparation of chitosan manganese-ferrite nanoparticles (cmn-fe nps) and evaluated its ability for the mice macrophage ...

FeO ⋅ Fe2O3 nH2O, Fe2.95Gd0.05O4 and Fe2.9Gd0.1O4 powders were obtained by chemical precipitation from aqueous solutions. The phase composition local environment of iron ions in gadolinium-doped oxide nanoparticles studied X-ray diffraction analysis nuclear gamma resonance (NGR) spectroscopy. Interpretation radiographs NGR spectra synthesised samples indicates the presence a superposition maghe...

The atomic structure and properties of nanoparticulate Fe2O3 are characterized starting from its smallest Fe2O3 building unit through (Fe2O3)n clusters to nanometer-sized Fe2O3 particles. This is achieved by combining global structure optimizations at the density functional theory level, molecular dynamics simulations by employing tailored, ab initio parameterized interatomic potential function...