Objetivo: En este estudio se evaluó el efecto de la modificación con óxido zinc del soporte convencional en catalizadores hidrodesulfuración (HDS) a base polioxometalato Anderson-Evans NiMo5W. Metodología: Los fueron sintetizados por método co-precipitación NiMo5W sobre Al2O3. caracterizaron FRX, MEB/EDS, CHONS, propiedades texturales, FT-IR, Raman y titulación potenciométrica n-butilamina. Res...

Incipient wetness impregnation was used to deposit dispersed tin (Sn) atoms on γ-Al2O3. The morphology and structure of the catalysts were characterized using Raman, X-ray Photoelectron Spectroscopy (XPS), low energy ion scattering (LEIS) combined with N2-physisorption in situ infrared diffuse reflectance spectroscopy (DRIFTS) NH3 CO2 as probe molecules, H2- temperature-programmed reduction (H­...

Abstract: The catalytic hydrogenation of lignin-derived monophenols with high efficiency and selectivity is important for the sustainable production of chemicals and fuels. Here, Pd/γ-Al2O3 was prepared via impregnation and used as catalyst for the hydrogenation of phenols to cyclohexanols under mild conditions in aqueous solution. 3 wt. % Pd/γ-Al2O3 exhibited good catalytic activity for the se...

A series of experiments were performed for toluene decomposition from a gaseous influent at normal temperature and atmospheric pressure by nonthermal plasma coupled with a combination of catalysts technology. Nonthermal plasma was generated by dielectric barrier discharge. γ-Al2O3 was used to be a sorbent and a catalyst carrier. Nanocatalysts were MnO2/γ-Al2O3 coupled with modified ferroelectri...

Introduction Alkaline earth oxides (AEOs) such as BaO have received considerable attention for their application in the lean-burn engine NOx storage/reduction (NSR) technology [1]. Previous experimental investigations have indicated that barium nitrate is the most stable form of the stored NOx in Ba-containing NSR catalysts. Two distinctive types of barium nitrates, Ba(NO3)2, i.e. “surface” and...

Four catalysts—1%Pd-2%Mn/γ-Al2O3, 1%Pd/γ-Al2O3, 2%Mn/γ-Al2O3 and γ-Al2O3—were synthesized via a sol–gel method characterized using various techniques to evaluate their physicochemical, textural, surface acidic properties. They were used in the catalytic transformation of ozone nitrogen oxides situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) analysis. Different consecuti...

A numerical investigation has been carried out applying single phase approach on turbulent forced convection flow of water based Al2O3 and TiO2 nanofluids flowing through a horizontal circular pipe under uniform heat flux boundary condition applied to the wall. The effect of volume concentrations, Brownian motion and size diameter of nanoparticles on flow and heat transfer have been examined fo...

A heat exchanger using nanofluid needs to operate at optimum mass concentration level to get the maximum heat transfer performance. A numerical analysis is performed on the heat transfer and pressure drop of water-based γ-Al2O3 nanofluid gasketed-plate heat exchanger to specify its optimum conditions. Cold water will be heated by γ-Al2O3/water nanofluid. The results showed that optimal volume c...

The effects of ceria and zirconia on the structure-function properties of supported rhodium catalysts (1.6 and 4 wt % Rh/γ-Al2O3) during CO exposure are described. Ceria and zirconia are introduced through two preparation methods: 1) ceria is deposited on γ-Al2O3 from [Ce(acac)3] and rhodium metal is subsequently added, and 2) through the controlled surface modification (CSM) technique, which i...