metal complexes, ml (m=ni, cu, co and zn) of unsymmetrical tetradentate schiff base have been synthesized by the template reaction of the half-units n-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine)(hl1) with 2-pyrroleca-rbaldehyde. the complexes have been characterized by elemental analysis, ir, 1h nmr and uv spectroscopy. the crystal structure of the ni(ii) complex has been determine...

the composite powders of barium-magnesium ferrite were prepared using sol-gel auto-combustion and microwave methods. the crystal structure and the shape of nanocomposites have been compared. x-ray diffraction (xrd), scanning electron microscope (sem) and vibrating sample magnetometer (vsm) were used to investigate the structural, morphological and magnetic properties of nanopowder. the formatio...

The crystals of [WS (CuNCS) ] anion have been isolated from CH ,CI solution and examined by X-ray structural analysis as well as by IR spectroscopy. The unit cell is monoclinic with a= 14.3796(13), b= 18.039(1 I), c= 22.5956(23)& P= 96.053(8)', space group P2,/n (14), Z= 4. The crystal structure was refined by the least-squares calculations to a final R-value of 0.0398(Rw= 0.0443) for 2777 u...

The synthesis and single-crystal X-ray structure determination of the title compound (phen)Pb(02CMe) is described. The complex crystallizes in the monoclinic space group P2 /c, a = 7.823(3), b = 12.421(4), c = 9.262(2) ?, ? = 79.92(3)", Z = 4, yielding R 0.048 for 3210 independent reflections. The coordination number around the lead atom is six. [Pb-N 2.54(2), 2.56(4)],[Pb-0, 2.19-2.22]

the synthesis and single-crystal x-ray structure determination of the title compound [(bipy) , pb(0 ,cme) (o clo )] (1) and [(bipy) pb(clo ) ] (2) is described. compound (i) crystallizes in the triclinic space group p1(2), a= 7.384(2), b= 12.824(3), c= 10.622(6) a, ?= 73.41(2), ?= 80.98(2), ?= 73.68(2)', z= 2, and r =0.033 for 3408 independent reflections .compound (2) crystallizes in the ...

objective(s): the current study reports the production and biocompatibility evaluation of a ternary nanocomposite consisting of ha, pla, and gelatin for biomedical application.materials and methods: hydroxyapatite nanopowder (ha: ca10(po4)6(oh)2) was produced by burning the bovine cortical bone within the temperature range of 350-450 oc followed by heating in an oven at 800. synthesis of the te...

crystalline antimony sulfide (sb2s3) with nanorods morphology was successfully prepared via hydrothermal method by the reaction of elemental sulfur, antimony and iodine as starting materials with high yield at 180°c for 24h.using oxidation reagents like iodine as an initiator of redox reaction to prepare sb2s3 is reported for first time. crystal growth of sb2s3 was done by increasing reaction t...

We report the crystal structure of the 5-residue peptide acetyl-YEQGL-amide, determined directly from powder X-ray diffraction data recorded on a conventional laboratory X-ray powder diffractometer. The YEQGL motif has a known biological role, as a trafficking motif in the C-terminus of mammalian P2X4 receptors. Comparison of the crystal structure of acetyl-YEQGL-amide determined here and that ...

First principle calculations of periodic crystal structure were successfully combined with powder X-ray diffraction measures to determine the structure of orotaldehyde monohydrate. This approach was particularly helpful to overcome the inadequacy of powder X-ray diffraction to reliably locate the hydrogen atoms of the intermolecular bond network of the crystal molecules. Density functional calc...