Abstract Nanoscaled-VPO (vanadium phosphate oxide) catalysts have been prepared on an alumina support with the objective of obtaining crystallites active phase a high surface-to-volume ratio. Since catalysed reaction occurs at surface, these nanoscaled allows studying surface species transformations minimized signal from bulk dominion. The chemical environment and oxidation state has determined...

Assumptions of individual rationality and preference stability provide the foundation for a convenient and tractable modeling approach. While both of these assumptions have come under scrutiny in distinct literatures, the two lines of research remain disjointed. This study begins by explicitly linking the two literatures while providing insights into perhaps the central issue facing behavioral ...

Computers can be very helpful to us by performing tasks on our behalf. For example, they are very good at performing calculations, storing information and producing visualisations of objects that do not yet exist as a made artifact. Increasingly, however, a different role is being found for the computer. It is the role of a catalyst, or a stimulant, to our own creative thinking. In such cases t...

A simple and efficient synthesis of aryl and heteroaryl substituted pyrimidines has been developed via initial Knoevenagal, subsequent addition and final cyclization of aldehyde, ethylcyanoacetate and guanidine nitrate. Piperidine has been used as a catalyst. Short reaction time, environment friendly procedure and excellent yields are the advantages of this procedure. All synthesized compounds ...

Catalyst selectivity is associated with well-defined homogeneous active sites. Transition metal complexes and organocatalysts are highly active and selective in the homogeneous phase, and their heterogenization by incorporating them into inorganic solid materials allows combining their excellent catalytic activity with improved separation, recovering and recycling properties. In this article, w...

The aim of this paper is to analyze how different catalyst activity profiles influence the operating strategies of industrial reactors. Based on this analysis a method that can be used to transform information given by laboratory reactor experiments into a form which can be used to estimate the productivity of the catalyst and the quality properties of polymers under industrial conditions is pr...

Nowadays, the interaction between systems is absolutely essential to achieve business continuity due to the need of exchanging and sharing services and resources. Unfortunately, this does not come without security problems. The organizations (companies, enterprizes, etc.) have to manage accesses to their services and resources by external opponents. O2O is a formal approach we suggest in this p...

The heteronuclear oxo-cluster [VPO4](•+) is generated via electrospray ionization and investigated with respect to both its electronic structure as well as its gas-phase reactivity toward small hydrocarbons, thus permitting a comparison to the well-known vanadium-oxide cation [V2O4](•+). As described in previous studies, the latter oxide exhibits no or just minor reactivity toward small hydroca...

Two novel hydrodesulfurization (HDS) catalysts: FeN4/C and FeN2/C, were prepared using an impregnation-pyrolysis method. The two materials were investigated as catalysts for hydrodesulfurization (HDS) and hydrodearomitization (HDA) of model compounds. The turnover frequency of the two FeN catalysts is comparable to (FeN4/C) or even higher (FeN2/C) than that of MoNi/Al2O3. The FeN4/C catalyst al...