The redox mechanism of two trisubstituted triazole-linked phenyl derivatives (CL41 and CL42) and a disubstituted triazole-linked phenyl derivative (CL2r50) were studied using cyclic, differential pulse and square wave voltammetry at a glassy carbon electrode. The CL41, CL42 and CL2r50 oxidation is a complex, pH-dependent irreversible process involving the formation of electroactive products tha...

Voltammetric detection of the toxic Zn ion was investigated using a fluorine-doped graphite pencil electrode (FPE). It is notable from the study that pencils were used as reference and working electrodes. In all the experiments, a clean seawater electrolyte solution was used to yield good results. The analytical working range was attained to 10 μgL(-1). The optimized voltammetric condition was ...

Hydrazine has been identified as a carcinogenic mutagenic, hepatotoxic, and neurotoxin material. A metal-organic framework with tetragonal symmetry, DMOF-1 (Zn2(bdc)2dabco) was synthesized by a versatile and facile technique, followed by its efficient development and validation as hydrazine electrochemical sensor. Differential pulse voltammetry (DPV), linear sweep voltammetry (LSV), and c...

The development of an electrochemical detector to monitor the in situ formation of biofilms is described. The detector consisted of an electrochemical cell containing three electrodes, whose response to the application of a potential profile to the working electrode was sensitive to the amount of biofilm present on the surface. The electrochemical technique used was repetitive cyclic voltammetr...

In the present work, tungsten disulfide was synthesised and characterised by using X-ray diffraction scanning electron microscopy. This material employed to modify a glassy-carbon electrode analyse clenbuterol. The results show that displays electrocatalytic activity toward clenbuterol oxidation. proposed technique is prospective for examination. limit of detection linear range are 0.51 mM 1–21...

Increasing urbanization and industrialization lead to the release of metals into the biosphere, which has become a serious issue for public health. In this paper, the direct electrochemical reduction of zinc ions is studied using electrochemically reduced graphene oxide (ERGO) modified glassy carbon electrode (GCE). The graphene oxide (GO) was fabricated using modified Hummers method and was el...

Vu D.L., Ertek B., Dilgin Y., Červenka L. (2015): Voltammetric determination of tannic acid in beverages using pencil graphite electrode. Czech J. Food Sci., 33: 72–76. The pretreated pencil graphite electrode (Pre-PGE) prepared by a chronoamperometry technique was applied for the determination of tannic acid using anodic stripping differential pulse voltammetry. The currents obtained from volt...

Square-wave cathodic adsorptive stripping voltammetry based on adsorptive accumulation is a very sensitive technique for the trace determination of xanthosine 50-monophosphate (50-XMP) and xanthosine 50-diphosphate (50-XDP). The determination is based on the strong interaction of the adsorption of xanthosine phosphate compounds on a mercury electrode surface, forming Hg(II)-xanthate. The cathod...

The determination of chromium(VI) at high concentrations can be performed spectrophotometrically with 1,5-diphenylcarbazite. The standard determination methods for chromium(VI) in leather like DIN53314 or IUC 18 have a detection limit of 3mg/kg leather. However the detection limit is not enough for lower concentrations. There is a need for lower detection limits because public awareness of hexa...

This study investigated the oxidation of ascorbic acid (Vitamin C) using a platinum nanoparticle electrode coated with an iodine monolayer, called a modified electrode. The electrode were grown using the cyclic voltammetry technique and the electrochemical measurements were taken using the cyclic voltammetry and chronoamperometric technique. In the case of platinum nanoparticle electrode modifi...