three new rimantadine schiff bases (rsbs) were prepared, and then the interaction of rsbs with bovine serum albumin (bsa) was investigated using fluorescence, synchronous fluorescence, uv-vis absorption spectroscopy under physiological conditions. the results showed that the three rsbs effectively quenched the intrinsic fluorescence of bsa via static quenching. binding constant (ka), number of ...

Nowadays, the use of lasers and other biospectroscopic techniques such as Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), Mass, UV-Vis, FT-Raman, 1HNMR, 13CNMR and 31PNMR spectroscopies have had significant progress in treatment of cancer diseases [1-17]. Process of irradiation transmission and absorption in human cells’ tissues is very important in diagnosis an...

A convenient synthetic scheme was developed to access a series of square-planar Pt(II) complexes of the form (TBA)[Pt(CN)3(CNR)] (TBA = tetra-n-butyl ammonium cation, R = CH3, c-C6H11, p-(C2H5)-C6H4). These heteroleptic complexes were characterized by combustion analyses, single-crystal X-ray structure determinations, HRFAB-MS, (1)H NMR, ATR-IR, solution UV-Vis, and solid-state emission spectro...

The properties of two forms of polyaniline (PAni) synthesised under acidic and basic conditions have been investigated both individually and as combined complexes. The PAni polymerised within alkaline media was redox inactive and non-conducting while the PAni emeraldine salt (ES) was electroactive and conducting. Raman, electron spin resonance, UV-Vis and fluorescence spectroscopies were used t...

Two tris(2-aminoethyl)amine (tren) based tripodal amide fluoroionophores, 1 and 2, functionalized with quinoline (chelating fluorophore) and naphthalene (non-chelating fluorophore) respectively, are synthesized in good yields. Fluoroionophore 1 shows a selective UV-Vis spectral shift in the case of Hg(2+) in acetonitrile among different metal ions like Li(+), Na(+), Ca(2+), Mg(2+), Cr(2+), Mn(2...

The effects of temperature, pH and long-term storage on the secondary structure and conformation changes of bovine haemoglobin (bHb) were studied using circular dichroism (CD) and ultraviolet--visible (UV-vis) spectroscopies. Neural network software was used to deconvolute the CD data to obtain the fractional content of the five secondary structures. The storage stability of bHb solutions in pH...

Metal (II) complexes of Co, Ni, Cu and Zn with Amoxicillin derivative (L) were synthesized identified by elemental analysis CHNS Uv-Vis, FTIR, TGA, metal AA, magnetic susceptibility conduct metric measurement. the ligand behaves as a bidentate. All that have nickel, copper , cobalt zinc ions proposed octahedral geometry shape. Protection study corrosion behavior carbon steel surface was conduct...

in this study at first , an azo dye, 2,7- naphthalenediol, 2-[(4-bromophenyl)azo (bpand) as a ligand has been synthesized by addition of p-bromoaniline to the modified montomorillonite k10 clay. this ligand was characterized using 1h-nmr, uv-vis and ir spectroscopies. subsequently, its interaction with calf thymus deoxyribonucleicacid ,ct-dna was investigated in 5 mm phosphate buffer solution, ...

Silver nanoclusters were synthesized and passivated by glutathione (GSH) ligand, with high aqueous stability and powerful red fluorescence and UV-vis yellow colour. Importantly, the specific recognition of the AgNCs was modulated from Hg(2+) ions to Cu(2+) ions upon the GSH passivation, of which the unique GSH-Cu(2+) chelating reaction could conduct the fluorescence quenching of AgNCs. Strong U...