A new class of dual fluorescent chemosensors for nitroaromatic compounds (NACs) based on phosphonated pyrene derivatives is reported, showing high selectivity towards trinitrotoluene (TNT). The strong intermolecular interactions (π-π stacking and hydrogen bonding) allow high fluorescence quenching with visual detection in short response times.

land mines are one of the tragic problems to human security in many countries. among many techniques suggested detecting landmines, plant-based detectors can be used as a reliable tool for unexploded ordnance detection. this study was conducted to determine different concentrations effect of trinitrotoluene (0, 5, 10, 15, 20, 30, 45 and 60 ppm) on germination and early seedling growth of 6 spec...

Detecting hidden explosive devices in war zones and transportation hubs is a pressing concern. Current efforts have focused on sensing three commonly used powerful explosives: 2,4,6-trinitrotoluene (TNT), 1,3,5-trinitro-1,3,5-triazinane (RDX) and pentaerythritol tetranitrate (PETN) (Chart 1). The need for ultratrace detection of these low-volatility compounds has resulted in an intense interest...

Trinitrotoluene (TNT) absorption was assessed in groups of workers at two explosives factories by measuring the urinary concentrations of dinitroaminotoluene (DNAT) metabolites. DNAT was detected in most of the urine samples analysed and for postshift samples the mean (SD) concentration was 9.7 (7.9) mg/l (range 0.1-44 mg/l (n = 219)). Individual workers showed substantial day to day variations...

We developed quantum dot-engineered M13 virus layer-by-layer hybrid composite films with incorporated fluorescence quenchers. TNT is designed to displace the quenchers and turn on the quantum dot fluorescence. TNT was detected at the sub ppb level with a high selectivity.

The pressure-time profiles produced by initiation in free-air of four commercial sector explosives covering a range of velocities of detonation are reported. The results indicate that there are no significant differences in the blast wave shapes from the explosives when measured between 5 and 20 m from the initiation point. The dependence of peak overpressure and positive phase impulse on scale...

We detect trace residues of RDX and TNT by surface photofragmentation fragment detection in real time at ambient conditions. An infrared or visible laser generates signature, NO molecular fragments, and a second, low energy, ultraviolet laser facilitates their detection by resonance enhanced multiphoton ionization. We present the effects of pump laser wavelength, laser energy, delay timing betw...

The co-adsorption of trinitrotoluene (TNT), a typical π-electron acceptor, and triphenylene (TP), a typical π-electron donor, on a Au(111) surface was investigated by in situ Electrochemical Scanning Tunneling Microscopy (ECSTM). DFT calculations proved that parallelly stacked and well-overlapped TP and TNT molecules can form Donor-Acceptor dyads through intermolecular π-π charge transfer, whic...