نتایج جستجو برای: trimethylsilyl cyanide
تعداد نتایج: 10439 فیلتر نتایج به سال:
The selectivities of nucleophilic substitution reactions of tetrahydropyran acetals promoted by trimethylsilyl trifluoromethanesulfonate depend upon the reaction solvent. Polar solvents favor the formation of S(N)1 products, while nonpolar solvents favor S(N)2 products. Trichloroethylene was identified as the solvent most likely to give S(N)2 products in both C- and O-glycosylation reactions.
Background and Objective: In the field of environmental risk assessment, Cyanide is one of the most important pollutants of water, soil and air that has an important impact on the ecosystem and environment of the contaminated area. Therefore, the present study aimed to prove the biological effectiveness of Vetiveria zizanioides in phytoremediation of soils contaminated with cyanide. Materials ...
'The development of a new, direct method for the preparation of dibenzo[a,e]cycloocta-1,5-dienes from phenylacetaldehyde by a double ortho Friedel-Crafts alkylation is described. When benzaldehyde (2b) is treated with trimethylsilyl iodide (3), a,n-diiodotoluene (6) is formed in high yield via the intermediacy of a-iodobenzyl trimethylsilyl ether (4b). Treatment of phenylacetaldehyde (%a) with ...
The [3+2]-cycloaddition of (trimethylsilyl)diazomethane (7) with 9H-fluorene-9-thione (1) at –60°C yields the spirocyclic 2,5-dihydro-5-trimethylsilyl-1,3,4-thiadiazole 10, which eliminates nitrogen at room temperature to give the 1,4-dithiane derivative 13 by dimerization of the intermediate fluorenethione (trimethylsilyl)methanide (11). This thiocarbonyl ylide can be trapped by 1 to give the ...
In the presence of magnesium and hexamethylphosphorictriamide, HMPT, trimethylchlorosilane, TMS-C1, reacts with cyanoepoxides to give related compounds. Ring cleavage at ? - position of cyanoepoxide, 1, followed by the addition of two trimethylsilyl groups leads to 2 then substitution of OSiMei by trimethylsilyl or H takes place to give ?, ? - bis (trimethylsilyl) nitrile or ? - trimethyls...
Backgrounds and Objectives: Cyanide is a species of high toxicity that found mostly in industrial effluents such as electroplating, metal mining, metallurgy and metal cleaning processes. Intrance of it to Existence enviroment contains very health hazardous. Purpose of this study, efficiency compare of both sonochemical and photosonochemical technologies for cyanide removal from aqueous solution...
in order to detect hydrogen cyanide gene and to determine pseudomonas fluorescent efficiency in producing hydrogen cyanide for controlling the growth of rhizoctonia solanipathogen (the causal agent of sugar beet root and crown rot), samples were collected from sugar beet rhizosphere in sabzevar fields. after soil sampling and purification, 31 pseudomonas spp. isolates were separated on specific...
Diazo(trimethylsilyl)methylmagnesium bromide readily reacted with various ketones and aldehydes to give the corresponding 2-diazo-(2-trimethylsilyl)ethanols. These were efficiently converted to indazoles bearing hydroxymethyl units at the 3-position by intermolecular [3 + 2] cycloaddition with benzynes.
Background and purpose: Cyanide (CN-) is of dangerous pollutants in the environment from industries such as electroplating, mining and paint entering into environment. The present study aimed to review the efficiency of cyanide removal by zirconia photocatalytic process with and without hydrogen peroxide (H2O2). Materials and methods: This was an applied-fundamental study and was conducted in ...
Hydrothermal reactions of a lead(II) salt with 3-aminopyrazine-2-carboxylic acid (HL1) gave rise to a series of lead(II) coordination compounds (1–6) having zero, one, two and three dimensional structures. X-ray diffraction structural analyses reveal that complexes [Pb(L1)2]2 (1) and [Pb(L1)(OCHNH2)(η-OCHO)]2 (2) possess dinuclear structures, containing a centre of symmetry. Complexes [Pb2(L1)4...
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