Density functional calculations of thio effects on the in-line mechanism of methanolysis of ethylene phosphate (a reverse reaction model for RNA phosphate transesterification) are presented. A total of 12 reaction mechanisms are examined using the B3LYP functional with large basis sets, and the effects of solvation were treated using the PCM, CPCM, and SM5 solvation models. Single thio substitu...

In this work, optimization of supercritical methanol extraction and transesterification for the production of biodiesel was investigated using Jatropha curcas L. seeds. Several important process parameters including heat pre-treatment (45°C-105°C for 12 and 24 hours), particle size (0.5 mm-2.0 mm) and temperature (200°C-300°C) were being studied by varying one factor at a time. The experiment w...

In this study, we investigated a fluidic system that adheres to new concepts of energy production. To improve efficiency, cost, and ease of manufacture, a millimetrically scaled device that employs a droplet-based co-axial fluidic system was devised to complete alkali-catalyzed transesterification for biodiesel production. The large surface-to-volume ratio of the droplet-based system, and the i...

Biodiesel production is worthy of continued study and optimization of production procedures due to its environmentally beneficial attributes and its renewable nature. Heterogeneous transesterification is considered to be a green process. The process requires neither catalyst recovery nor aqueous treatment steps and very high yields of methyl esters can be obtained, close to the theoretical valu...

Background The production of fuels and chemicals from renewable resources is increasingly important due to the environmental concern and depletion of fossil fuel. Despite the fast technical development in the production of aviation fuels, there are still several shortcomings such as a high cost of raw materials, a low yield of aviation fuels, and poor process techno-economic consideration. In r...

This study is based on optimizing the experimental conditions of biodiesel production by base-catalyzed transesterification using waste cooking oil (WCO). In this study, the key parameters varied were methanol (20, 25, 30, 35, and 40%), sodium hydroxide (0.4, 0.6, 0.8, 0.9 and 1.0g), reaction time (40, 60, 90, 100 and 120 minutes) and reaction temperature (50, 52, 55, 58, and 60 C). Maximum bio...

Currently, most of the biodiesel is produced from the edible/refined type oil using methanol and alkaline catalyst. However, large amount of non-edible type oils and fats are available in our country. In this study, crude neem oil is used as alternative fuel for biodiesel production. The difficulty with alkaline transesterification of these oils have contained large amounts of free fatty acids ...