This paper gives a general view of a recently developed thermodynamic model of the thermoelastic rnartensitic transformation. Unlike existing empirical, mathematical or thermodynamic models, this generalised thermodynamic model can be used to understand and describe quantitatively the overall thermomechanical behaviour of polycrystalline shape memory alloys. Important points of difference betwe...

It is often incorrectly assumed that the number of microstates Ω(E, V, N, ...) available to an isolated system can have arbitrary dependence on the extensive variables E, V, N, ... However, this is not the case for systems which can, in principle, reach thermodynamic equilibrium since restrictions arise from the underlying equilibrium statistical mechanic axioms of independence and a priori equ...

Recent advances in modeling thermodynamic and transport properties of electrolyte solutions are reviewed. In particular, attention is focused on mixed-solvent electrolyte models, equations of state for high-temperature and supercritical electrolyte systems and transport property models for multicomponent, concentrated solutions. The models are analyzed with respect to their capability of comput...

Reverse micellar systems are nanofluids with unique properties that make them attractive in high selectivity separation processes, especially for biological compounds. Understanding the phase behavior and thermodynamic properties of these nanosystems is the first step in process design. Separation of components by these nanosystems is performed upon contact of aqueous and reverse micellar phase...

Allostery pervades macromolecular function and drives cooperative binding of ligands to macromolecules. To decipher the mechanisms of cooperative ligand binding it is necessary to define at a microscopic level the structural and thermodynamic consequences of binding of each ligand to its allosterically coupled site(s). However, dynamic sampling of alternative conformations (microstates) in allo...

In “Is the Frobenius Matrix Norm Induced?”, the authors ask whether the Frobenius and the norms are induced. There, they claimed that the Frobenius norm is not induced and, consequently, conjectured that the norm may not be induced. In this note, it is shown that the Frobenius norm is induced on particular matrix spaces. It is then shown that the norm is in fact induced on a particular matrix-v...

We present an algorithm to evaluate large deviation functions associated to historydependent observables. Instead of relying on a time discretisation procedure to approximate the dynamics, we provide a direct continuous-time algorithm valuable for systems with multiple time scales, thus extending the work of Giardinà, Kurchan and Peliti [1]. The procedure is supplemented with a thermodynamic-in...