In this paper, we explore the emergence and direct interaction of two different types of dissipative structure in a single system: self-replicating chemical spot patterns and buoyancyinduced convection rolls. A new Lattice Boltzmann Model is developed, capable of simulating fluid flow, heat transport, and thermal chemical reactions, all within a simple, efficient framework. We report on a first...

In this article, a wet chemical method was developed to prepare stable CuO nanofluids. The influences of synthesis parameters, such as kinds and amounts of copper salts, reaction time, were studied. The thermal conductivities of CuO nanofluids were also investigated. The results showed that different copper salts resulted in different particle morphology. The concentration of copper acetate and...

Skin irritation is mostly a multifactorial process. Competitive effects of different chemical irritants are well known. This study investigates the influence of a thermal stimulus on skin pre-irritated with sodium lauryl sulfate (SLS). Seventy-seven volunteers were patch-tested with SLS 0.25% and 0.5% for 48 h. Water served as control. Skin reaction was evaluated by measurement of transepiderma...

This paper deals with the steady state catalytic ignition of premixed gases over a flat píate of finite thickness. An external heat flux is added to the píate to facilítate the ignition process. The influence of the finite thermal conductivity of the píate on the catalytic ignition is evaluated in the two distinct limits of the reduced Damkohler number of order of unity and much less than unity...

In the present study, consider an influence of chemical reaction on an unsteady MHD free convective, viscous dissipative Casson fluid flow over a vertically inclined plate in presence of magnetic field, heat and mass transfer. The modeling equations are converted to dimensionless equations, then solved through finite element technique. Computations were performed to analyze the behavior of flui...

This exploration addresses MHD stagnation point Powell Eyring nanofluid flow with double stratification. The effects of thermal radiation and chemical reaction are added in temperature and nanoparticle concentration fields respectively. Furthermore, appropriate transformations are betrothed to obtain nonlinear differential equations from the system of partial differential equations and an analy...

Cumene Hydroperoxide (CHP) has been used in the production of Dicumyl Hydroperoxide (DCPO) and phenol. In Taiwan, several severe fire or explosion incidents have occurred due to its thermal instability or reactivity. In this research, the exothermic decomposition of CHP in Cumene was characterized by isothermal microcalorimeter, TAM (thermal activity monitor), because isothermal testing offers ...

Detailed knowledge of thermal conversion processes becomes increasingly important in order to formulate mathematical models for the design and optimization of chemical reactors employed in energy and chemicals recovery from biomass. Since heat of reaction has an important influence on the course of thermal conversion, the corresponding kinetic models should be coupled with heat transfer equatio...

The molecular machine in biological systems works as a chemical energy transducer. For instance, the protein motors such as myosin and kinesins, or flagellar motor produce mechanical energy as they consume the chemical energy provided by hydrolysis of ATP or proton density gradient. Some other proteins, such as enzymes or pump proteins of membrane transportation, can be also thought as chemical...

A fundamental issue in the field of reaction dynamics is the inclusion of the quantum mechanical (QM) effects such as zero point energy (ZPE) and tunneling in molecular dynamics simulations, and in particular in the calculation of chemical reaction rates. In this work we study the chemical reaction between a muonium atom and a hydrogen molecule. The recently developed ring polymer molecular dyn...