We have studied the rheological properties of mixtures of polyoxyethylene (10 mol) phytosterol (PhyEO(10)) and polyoxyethylene (10 mol) cholesterol (ChEO(10)) mixed in different ratios along with tetraethylene glycol monododecyl ether (C(12)EO(4)) surfactants in water. Addition of C(12)EO(4) to the aqueous solution of a mixture of (PhyEO(10) + ChEO(10)) results in one-dimensional micellar growt...

A series of novel imidazolium salts bearing hydrophilic tetraethylene glycol (TEG) and/or hydrophobic long-chain alkyl (n-C12) functionalities, which are precursors for desired N-heterocyclic carbene (NHC) ligands, were synthesized and characterized. Rh(I)-NHC complexes were prepared in good yields by the silver carbene transfer method with NHC-Ag species derived from the imidazolium salts. The...

Stable superparamagnetic iron oxide nanoparticles (SPIONs), which can be easily dispersed in an aqueous medium and exhibit high magnetic relaxivities, are ideal candidates for biomedical applications including contrast agents for magnetic resonance imaging. We describe a versatile methodology to render water dispersibility to SPIONs using tetraethylene glycol (TEG)-based phosphonate ligands, wh...

An unexpected and previously unknown resorcinarene mono-crown with a fused benzofuran moiety in its macrocyclic core was obtained as a byproduct from a bridging reaction of tetramethoxy resorcinarene with tetraethylene glycol ditosylate. The formation of the fused benzofuran moiety in the resorcinarene macrocycle resulted in a unique rigid and puckered boat conformation, as shown by XRD studies...

The carbon quantum dot (CQD) paper-based analytical device (PAD) has drawn great attention and is being intensively explored. However, the construction of a continuous flow CQD synthesis remains challenging. In this work, reaction apparatus was constructed to synthesize nitrogen-doped CQDs using mixed-solvent system tetraethylene glycol water. optical properties were characterized. found be que...

Resistive switching devices have garnered significant consideration for their potential use in nanoelectronics and non-volatile memory applications. Here we investigate the nonlinear current-voltage behavior and resistive switching properties of composite nanoparticle films comprising a large collective of metal-insulator-metal junctions. Silver nanoparticles prepared via the polyol process and...

The elastic shear modulus G and swelling pressure ω are studied for a basic, pH-responsive hydrogel synthesized by crosslinking copolymerization of co-monomers hydroxypropyl methacrylate and N,N-dimethylaminoethyl methacrylate with crosslinker tetraethylene glycol dimethacrylate. Under normal conditions of use as a "smart" material, hydrogel swelling ratio Q and pH vary simultaneously, but here...