The kinetics of the oxidation of Ru (III) catalyzed oxidation of tartaric acid by potassium bromate in aqueous perchloric acid medium at constant ionic strength was investigated in the temperature range 303318 K. The reactions exhibit first order kinetics at low concentration of bromate, tending to zero order at high concentration. Zero order kinetics with respect to [tartaric acid] and first o...

The hormetic effect is a toxicological phenomenon in the soil ecosystem. influence of low-molecular-weight organic acids (LMWOAs) on release and activation phosphorus (P) has become focus research. To what extent LMWOAs can regulate P then nutrients worth attention. This study aimed to investigate effects different types concentrations exogenous extraction, establish relationship between concen...

a one-pot synthesis of (s)-(-)-propranolol is reported. zn(no3)2/(+)-tartaric acid catalyzed enantioselective synthesis of (s)-(-)-propranolol via kinetic resolution of key intermediate ?-naphthyl glycidyl ether with high optical and chemical yield.

Cocrystal formation rates during dry grinding and liquid-assisted grinding were investigated by X-ray powder diffractometry and Raman spectroscopy. Two polymorphic forms of piracetam were used to prepare known piracetam cocrystals as model substances, i.e.,piracetam-citric acid and piracetam-tartaric acid cocrystals. Raman spectroscopy in combination with principal component analysis was used t...

Overexpression of epidermal growth factor receptor (EGFR) has been associated with cancer. Targeted inhibition of the EGFR pathway has been shown to limit proliferation of cancerous cells. Hence, we employed Traditional Chinese Medicine Database (TCM Database@Taiwan) (http://tcm.cmu.edu.tw) to identify potential EGFR inhibitor. Multiple Linear Regression (MLR), Support Vector Machine (SVM), Com...

Although the tartrates have been considered as possible metabolites in higher plants since the initial work of Pasteur in 1848, surprisingly little is known of their actual physiological significance. Vickery and Palmer (35) have briefly reviewed the history of (+)-tartrate in plants, including the problems of identification and of nomenclature. They conclude that (+)-tartrate is an uncommon pl...

This study was conducted to assess the compatibility of aspirin with selective amino acids by studying the effect of amino acids on the solubility of aspirin, so that the attention could be paid towards the use of proteinous foods along with aspirin. Two different types of dissolution media, i.e., 0.5% solution of each amino acid and 100 mL of distilled water (100 mL each), were prepared. Then,...