Controlling the bio-inspired redox conversion of Co(II)–disulfide compounds to their related Co(III)–thiolate complexes is a perplexing task as factors triggering this reaction are not fully understood. Three disulfide ligands 2,2?–disulfanediylbis(N,N-bis((3,5–dimethyl-1H–pyrazol–1–yl)methyl)ethan-1-amine) (LmpzSSLmpz), 3,3?-disulfanedylbis(N,N-bis(pyridin-2-ylmethyl)propan-1-amine) (LpSSLp), ...