a fiber coating from polyaniline (pani) was electrochemically prepared and employed for solid phase micreoextraction (spme). the pani film was directly electrodeposited on the platinum wire surface using cyclic voltametry (cv) technique. the same method was applied for the preparation of spme fiber coated by polyaniline multiwalled carbon nanotubes (pani/mwcnts) composite. the concentration of ...

• Validation of MHS-SPME-GC-MS method for the analysis two plasticizer metabolites. No matrix effect, no external calibration, loss, solvents free and quick method. Application to urine samples population with exposure plastics. In present work, an optimization validation analytical determination metabolites, 2-ethylhexanol 4-heptanone in urine, were carried out by multiple headspace solid-phas...

This paper describes the application of solid-phase microextraction (SPME) to cannabis testing in hair. Fifty milligrams of hair was washed with petroleum ether, hydrolyzed with NaOH, neutralized, deuterated internal standard was added and directly submitted to SPME. The SPME was analyzed by GC-MS. The limit of detection was 0.1 ng/mg for cannabinol (CBN) and delta9-tetrahydrocannabinol (THC) a...

This paper describes the use of headspace solid-phase microextraction (SPME) combined with gas chromatography to identify the signature odors that law enforcement-certified detector dogs alert to when searching for drugs, explosives, and humans. Background information is provided on the many types of detector dog available and specific samples highlighted in this paper are the drugs cocaine and...