A new composite mesoporous honeycomb material was developed to be a thermal energy storage medium that can contact the functional fluid directly. In our previous study, this honeycombed composite material acted as a promising sorption thermal energy storage medium in an open system, exhibiting a lower regeneration temperature as 80°C, high volumetric heat storage density, and high stability. In...

Pesticide sorption in soils is controlled by time-dependent processes such as diffusion into soil aggregates and microscopic sorbent particles. This study examines the rate-controlling step for time-dependent sorption in clay loam aggregates. Aggregates (5 mm) were stabilized with alginate, and adsorption of azoxystrobin, chlorotoluron, and cyanazine was measured in batch systems equilibrated f...

Article history: Received 17 October 2007 Received in revised form 11 February 2008 Accepted 26 February 2008 Available online 14 April 2008 Humin is an important fraction of soil organic matter that is known to tightly bind many organic compounds. The objective of this study was to evaluate the role of humin as a natural sorbent in soils irrigated with freshwater and treated wastewater. To mee...

In situ chemical oxidation is a commonly applied soil and groundwater remediation technology, but can have significant effects on soil properties, which in turn might affect fate and transport of organic contaminants. In this study, it was found that oxidation treatment resulted mainly in breakdown of soil organic matter (SOM) components. Sorption of naphthalene and phenanthrene to the original...

Endosulfan (ES) is a micropollutant found in reverse osmosis concentrates from water reuse applications. Electrodialysis (ED) can remove and recover charged solutes from such concentrates. While polar compounds cannot normally be removed, their fate in ED is important as they can contribute to membrane fouling/poisoning and be released during cleaning. High adsorption of ES to ED membranes was ...

Batch experiments were carried out to investigate the effects of initial atrazine concentrations and consecutive desorption steps on the desorption characteristics of atrazine from a sandy loam soil. As initial atrazine concentration increased, the average percentage of atrazine desorption on the sandy loam soil ranged gradually from 23.1% to 38.5% after five consecutive desorption steps. The v...

The desorption behavior of benzidine from Lake Macatawa (Holland, MI, USA) sediment was investigated in this study using batch solvent extraction method. Seven solvents were tested as the extracting reagents: Deionized water (DI), calcium chloride in DI (CaCl2), sodium hydroxide in DI (NaOH), acetonitrile (ACN), a mixture of acetonitrile and ammonium acetate in DI (ACN-NH4OAc), methanol (MeOH),...

The incorporation of brown algae into biopolymer beads or foams for metal sorption has been previously reported. However, the direct use of these biomasses for preparing foams is a new approach. In this study, two kinds of porous foams were prepared by ionotropic gelation using algal biomass (AB, Laminaria digitata) or alginate (as the reference) and applied for Pb(II) sorption. These foams (ma...

Charcoal is found in water, soil, and sediment where it may act as a sorbent of organic pollutants. The sorption of organic compounds to natural solids often shows hysteresis. The purpose of this study was to determine the source of pronounced hysteresis that we found in the sorption of a hydrophobic compound (benzene) in water to a maple-wood charcoal prepared by oxygen-limited pyrolysis at 67...

Lignin, a natural renewable material, was incorporated in a series of polydimethylsiloxane/silica composites. Besides the effect as bulk filler, the presence of lignin determines the change of some properties among them being surface properties that were evaluated by contact angle and water sorption measurements. The contact angles were determined in static regime by using the sessile drop tech...