Triaryl-phosphines and -phosphites bearing fluorous ponytails give high rates, good linear selectivity and good retention of catalyst in the fluorous phase during hydroformylation of alkenes in fluorous solvents.

We describe the clinical evaluation of the nervous-system effects of solvent exposure. We review the current evidence in the epidemiological literature on neurotoxicological effects of solvents, and outline methods and issues to be taken into account in assessment of the patient whose symptoms may be related to solvent toxicity. Primary prevention of these disorders is essential, because treatm...

Deep eutectic solvents (DESs), as a novel class of green solvents, were successfully applied as eco-friendly and sustainable reaction media for fast surface modification of spherical porous silica, resulting in stationary phases for high-performance liquid chromatography. The new reaction media were advantageous over organic solvents in many aspects, such as the high dispersibility of silica sp...

Four organic amine-based solvents were discovered which enable direct exfoliation of graphite to produce high-quality and oxygen-free graphene nanosheets. These solvents outperform previously used solvents and additives such as N-methyl-pyrrolidone and surfactants in terms of their dispersing capacity. The resulting dispersions allow the facile fabrication of zeolitic imidazolate framework (ZIF...

Heterogeneous catalytic hydrogenation of cyclohexene, catalyzed by Pt/A1203, was carried out in thirteenvarious solvents (four alcoholic solvents, six aprotic polar solvents and three non polar solvents) at 25 °C.Single-parameter correlations of logk vs. normalized polarity parameter (ETN), hydrogen-bond acceptorbasicity (p), hydrogen-bond donor acidity (a) and dipolarity/polarizibility (it*) d...

Quantum mechanical calculations of different energies components of 1,10-phenanthroline in ground state were carried out by DFT method , in isolated state and in various solvents to study the effects of solvents on various energy components . The solvation energy, chemical potential, hardness, electrophilicity of 1,10-phenanthroline were calculated with the help of computed HOMO-LUMO gap of 1,1...

Organic solvents have long been recognized as being toxic to multiple organ systems. It is commonly known that exposure to organic solvents causes hematologic diseases, including hematologic cancers such as leukemia and lymphoma. A large body of literature has developed which shows that exposure to organic solvents causes kidney disease, especially chronic glomerulonephritis. A number of recent...

The conductivity of N al in ternary solvents consisting of water, alcohol and urea has been determined at 25 °C in its dependence on the alcohol concentration. Viscosities and static dielectric constants of these ternary solvents have also been measured. It has been found that in all studied solvents the limiting equivalent conductivities A0 are smaller than those in binary solvents despite of ...