In this contribution, an effective and soft method for removal of template from nanochannels of mesoporous silica (MCM-41) is proposed. This method is based on chemically-modified solvent extraction which enhanced by means of an auxiliary organic compound, i.e. benzene sulfonamide. Template removal was performed in soft condition, i.e. in the presence of diluted sulfuric acid and at ambient tem...

Abstract Green extraction processes to obtain high value bioactive compounds from raw natural materials and wastes has gained attention the past few years. In present study, we investigated a Natural Deep Eutectic Solvent derived two products, namely choline chloride glucose as potential solvent for of tannin spent coffee ground(SCG). A was used coagulant with Poly aluminium chloride(PAC) flocc...

OBJECTIVE To evaluate the amount of apically extruded debris during retreatment (with or without solvent) of root canals filled by two obturation techniques. MATERIALS AND METHODS Forty-eight root canals were prepared using ProTaper Universal F3 and filled with Gutta-percha and AH 26 sealer using single cone or lateral condensation techniques. The root canal fillings were removed using ProTap...

Selective formation of amorphous, nematic (N), and beta phases in poly(9,9-di-n-octyl-2,7-fluorene) (PFO) films was achieved via judicious choice of process parameters. Phase structure and film morphology were carefully examined by means of X-ray diffraction as well as electron microscopy. "Amorphous" thin films were obtained by quick evaporation of solvent. Slow solvent removal during film for...

The effects on the rate and activation parameters of a series of Menschutkin processes on changing from a molecular solvent to an ionic liquid were investigated. The removal of delocalised pi-systems from the reagents does not affect the change in activation parameters on changing solvent. In each of the cases investigated, rate accelerations observed on moving to the ionic liquid could be attr...

OBJECTIVES The aim of this in vitro study was to compare the efficacy of two retreatment rotary systems in the removal of Gutta-percha (GP) and sealer from the root canal walls with or without solvent. MATERIALS AND METHODS Forty-eight extracted human mandibular first premolars were prepared and obturated with GP and AH Plus sealer. Samples were then randomly divided into four groups. Group I...