Hydrogen peroxide has been identified as a stable intermediate of the electrochemical oxygen reduction reaction on various electrodes including metal, metal oxide and carbon materials. In this article we study the hydrogen peroxide oxidation and reduction reactions in alkaline medium using a rotating disc electrode (RDE) method on oxides of the perovskite family (LaCoO3, LaMnO3 and La0.8Sr0.2Mn...

It is expected that residential units may replace   traditional heat and power production systems with cogeneration ones. Among the different cogeneration systems, fuel cell based systems are a suitable choice due to their high efficiency, high power density, low emission and low noise. In this paper, a cogeneration system based on solid oxide fuel cells is examined. The system, including the f...

This study shows the design of a new hybrid power generation system, photovoltaic panel (PV)–coupled solid oxide fuel cell (SOFC) and gas turbine (GT)–electrolyser. Three objectives (cost, pollutant emissions, and reliability), which are usually in conflict, are considered simultaneously. The design of a hybrid system, considering the three mentioned objectives, poses a very complex problem of o...

Objectives • Develop the concept of a solid oxide fuel-fed electrolysis cell (SOFEC) for hydrogen production. • Identify and develop SOFEC cathode materials that are electrocatalytically and chemically stable in both reducing and oxidizing atmospheres. • Develop a novel concept of a composite/hybrid planar SOFEC-solid oxide fuel cell (SOFC) stack to co-generate hydrogen and electricity. • Demon...

This study provides a step-by-step, up-to-date fuel cell fundamentals, thermodynamic and electrochemical principles, system evaluation factors via case of 10-kW alkaline designed to operate in space applications. The also produces 100 kg pure water 5.5 kW heat. is modelled using MATLAB ANSYS Fluent. Then, the model verified with theoretical experimental results from literature. A parametric var...

We present here a critical review of several technologically important electrocatalytic systems operating in alkaline electrolytes. These include the oxygen reduction reaction (ORR) occurring on catalysts containing Pt, Pd, Ir, Ru, or Ag, the methanol oxidation reaction (MOR) occurring on Pt-containing catalysts, and the ethanol oxidation reaction (EOR) occurring on Ni-Co-Fe alloy catalysts. Ea...

Alkaline polyelectrolyte fuel cell now receives growing attention as a promising candidate to serve as the next generation energy-generating device by enabling the use of non-precious metal catalysts (silver, cobalt, nickel et al.). However, the development and application of alkaline polyelectrolyte fuel cell is still blocked by the poor hydroxide conductivity of anion exchange membranes. In o...