Gas-phase laser Raman spectroscopy has recently been adopted to determine the concentrations of relevant gaseous species within the anode flow channel with high spatial and temporal resolution during operation at technically relevant operating conditions. The paper describes the configuration of an optically accessible SOFC, the laser system and optical setup for 1 D Raman spectroscopy as well ...

Considerable attention has been focused on solid oxide fuel cells (SOFCs) due to their potential for providing clean and reliable electric power. However, the high operating temperatures of current SOFCs limit their adoption in mobile applications. To lower the SOFC operating temperature, we fabricated a corrugated thin-film electrolyte membrane by nanosphere lithography and atomic layer deposi...

an efficient procedure is presented for the evaluation of solid oxide fuel cell (sofc) anode microstructure triple phase boundary length (tpbl). triple phase boundary- the one that is common between three phases of the microstructure- has a great influence on the overall efficiency of sofc because all electrochemical reactions of anode take place in its vicinity. therefore, evaluation of tpbl f...

Recent developments in solid-oxide fuel cells (SOFC) that electrochemically oxidize hydrocarbon fuels to produce electrical power without first reforming them to H2 are described. First, the operating principles of SOFCs are reviewed, along with a description of state-of-the-art SOFC designs. This is followed by a discussion of the concepts and procedures used in the synthesis of direct-oxidati...

The radiation effect within the solid anode, electrolyte, and cathode SOFC layers problem has been investigated in this paper. Energy equation is solved by the Lattice Boltzmann method (LBM). The Rosseland method is used to model the radiative transfer in the electrodes. The Schuster-Schwarzschild method is used to model the radiative transfer in the electrolyte. Without radiatve effect, the fo...

a two-dimensional cfd model of a planar solid oxide fuel cell (sofc) has been developed.this model can predict the performance of sofc at various operating and design conditions.the effect of knudsen diffusion is accounted in the porous electrode (backing) and reaction zonelayers. the mathematical model solves conservation of electrons and ions and conservation ofspecies. the model is formulate...

In this paper, a hybrid solid oxide fuel cell (SOFC) and micro gas turbine (MGT) power system is parametrically studied to evaluate the effect of different operating conditions. The SOFC/MGT power system includes SOFC reactor, combustion chamber, compressor and turbine units, and two heat exchangers. The effects of fuel utilization, temperature, and pressure are assessed on performance of t...

Biogas can be currently considered as an alternative option for electricity production, mainly due to its high energy content (hydrocarbon-rich source), its renewable status and its relatively low utilization cost. Solid Oxide Fuel Cell (SOFC) stacks convert fuel’s chemical energy to electricity with high efficiencies and reveal significant advantages on fuel flexibility combined with lower emi...