The characteristics of enzymatic/mild acidolysis lignin (EMAL) isolated from moso bamboo were investigated using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Pyrolysis temperature as a factor on products was studied, and the pyrolysis mechanism was inferred with respect to the dominating products. Research results showed that pyrolysis products derived from EMAL pyrolysis were mai...

The pyrolysis of TVSb has been investigated in a flow tube reactor using Dz and He carrier gases. For TVSb alone, the most likely pyrolysis reaction involves an Sbcentered reductive elimination pathway. A less likely possibility is pyrolysis via homolysis of the Sb-C bonds, yielding vinyl radicals. Unfortunately, examination of the organic byproducts in both He and D, yields insufficient inform...

The effect of corn stover lignin structure alteration caused by white-rot fungi pretreatment on the pyrolysis kinetics was studied by FTIR and TG/DTA. Results showed that biopretreatment had a remarkable effect on lignin pyrolysis. Biopretreatment can decrease the activation energy and increase the pre-exponential factor in the initial stage of pyrolysis, which makes it possible to start the li...

The paper introducedeffects of modified pyrolysis tar on flue gas desulfurization. This experiment selected the pyrolysis tar as the raw material, researched the effects on desulfurization performance under different modification solution, concentration, solid liquid ratio of pyrolysis tar and modified solution, calcination temperature and calcination time by 16 group orth...

Analytical pyrolysis is a technique currently used for investigating structural features of complex macromolecular materials. However, pitfalls appear to be widespread in pyrolysis studies of humic substances, and serious limitations can be experienced during the analytical procedure due to thermal reactions and configuration of the pyrolysis units and chromatographic systems. Pyrolysis present...