in this study an easy, green, efficient and simple approach is reported for the synthesis of some benzothiazole-, benzimidazole- and benzoxazole-2-thiolderivatives. the proposed approach employs the reaction of corresponding aromatic amine with potassium isopropyl xanthate (z11) in the presence of copper sulfate (cuso4) as a catalyst under conventional heating and ultrasonic irradiation. the ad...

Maltose as an efficient, available, cheap and eco-friendly catalyst has been applied for the synthesis of 3,4,5-substituted furan-2(5H)one derivatives via a one-pot three-component reaction of arylamines, aromatic aldehydes and dialkyl acetylenedicarboxylates in water. This method has notable advantages in terms of simple workup, no need for column chromatography, short reaction time and high y...

Maltose as an efficient, available, cheap and eco-friendly catalyst has been applied for the synthesis of 3,4,5-substituted furan-2(5H)one derivatives via a one-pot three-component reaction of arylamines, aromatic aldehydes and dialkyl acetylenedicarboxylates in water. This method has notable advantages in terms of simple workup, no need for column chromatography, short reaction time and high y...

An efficient green route for the preparation of naphthoxazinones, applying a three-component one-pot condensation reaction of 2-naphthol, aromatic aldehyde and urea in the presence of nano silica supported ferric chloride under solvent-free conditions has been developed. The present procedure offers several advantages such as short reaction time, simple workup, recovery and reusability of the c...

a simple and rapid method has been developed for the determination of ascorbic acid in fruit and pharmaceutical products. the method is based on the measurement of the reaction rate between ammonium molybdate and ascorbic acid in acidic media. the reaction was monitored spectrophotometrically at 800 nm by fixed-time and variable-time methods. the calibration graph was linear in the range of 5 0...

The kinetic of photo oxidative decolorization of C.I. Acid yellow 23 (AY23) was investigated in UV/ process. The semi-logarithmic of the concentrations of AY23 versus irradiation time were linear, suggesting pseudo-first order reaction. A simple kinetic model is proposed which confirms pseudo- first order reaction. The results indicate that the apparent reaction rate constant is a function of l...

An improved, simple, and facile synthesis of 3,4-dihydropyrimidin-2(1H)-ones by employing three-component, one-pot condensation reaction of β-keto ester, aromatic aldehydes, and urea or N-methylurea using LaCl3/ClCH2COOH as an inexpensive and green chemistry catalyst system under solvent-free conditions described. Compared with the classicalBiginelli reaction conditions, this method has the adv...