Novel silicate nanoplatelets that induce osteogenic differentiation of human mesenchymal stem cells (hMSCs) in the absence of any osteoinductive factor are reported. The presence of the silicate triggers a set of events that follows the temporal pattern of osteogenic differentiation. These findings underscore the potential applications of these silicate nanoplatelets in designing bioactive scaf...

We present (29)Si, (27)Al, and (67)Zn NMR evidence to show that silicate ions in alkaline solution form complexes with zinc(II) (present as zincate, Zn(OH)(3)(-) or Zn(OH)(4)(2-)) and, concomitantly, with aluminate (Al(OH)(4)(-)). Zincate reacts with monomeric silicate at pH 14-15 to form [(HO)O(2)Si-O-Zn(OH)(3)](4-) and with dimeric silicate to produce [HO-SiO(2)-O-SiO(2)-O-Zn(OH)(3)](6-). The...

Calcium silicate compounds belong to a complicated class of silicates. Among their many industrial applications, calcium silicates are heavily used as a building material as they constitute the main ingredient in today’s cement clinker. We report here an extensive surface analysis of synthetic calcium silicate phases (tricalcium silicate, C3S, and dicalcium silicate, C2S) using first-principles...

Quasielastic and inelastic neutron scattering have been highlighted as excellent tools for studying the hydration of cement components. Here, the complimentary application of inelastic and time-resolved quasielastic neutron scattering to investigate the reaction kinetics during the crucial first 24 h of hydration will be highlighted. Some recent results include the interaction of tricalcium and...

The understanding and control of early hydration of tricalcium silicate (C₃S) is of great importance to cement science and concrete technology. However, traditional characterization methods are incapable of providing morphological and spectroscopic information about in situ hydration at the nanoscale. Using soft X-ray spectromicroscopy, we report the changes in morphology and molecular structur...

High-pressure experiments and theoretical calculations demonstrate that an iron-rich ferromagnesian silicate phase can be synthesized at the pressure-temperature conditions near the core-mantle boundary. The iron-rich phase is up to 20% denser than any known silicate at the core-mantle boundary. The high mean atomic number of the silicate greatly reduces the seismic velocity and provides an exp...

We report 3 13 μm spectroscopy of 4 comets observed between August 2002 and February 2003: C/2002 O4 (Hönig) on August 1, 2002, C/2002 V1 (NEAT) on Jan. 9 and 10, 2003, C/2002 X5 (Kudo-Fujikawa) on Jan. 9 and 10, 2003, and C/2002 Y1 (Juels-Holvorcem) on Feb. 20, 2003. In addition, we include data obtained much earlier on 69P/Taylor (February 9, 1998) but not previously published. For Comets Tay...

induction of systemic resistance to cucumber against marginal leaf blight disease caused by pseudomonas marginalis using silicon application (as 1 &2 mm of sodium silicate) was studied under greenhouse conditions. results indicated that application of 2 mm of sodium silicate remarkably increased resistance in cucumber against the pathogen. according to the results, disease severity in plants tr...

Determination of silicate concentration in seawater without addition of liquid reagents was the key prerequisite for developing an autonomous in situ electrochemical silicate sensor (Lacombe et al., 2007) [11]. The present challenge is to address the issue of calibrationless determination. To achieve such an objective, we chose chronoamperometry performed successively on planar microelectrode (...