The principal (13)C chemical-shift values for the pi-[TCNE](2)(2-) dimer anion within an array of counterions have been measured to understand better the electronic structure of these atypical chemical species in several related TCNE-based structures. The structure of pi-[TCNE](2)(2-) is unusual as it contains two very long C-C bond lengths (ca. 2.9 Angstroms) between the two monomeric units an...

Paramagnetic, or open-shell, systems are often encountered in the context of metalloproteins, and they are also an essential part of molecular magnets. Nuclear magnetic resonance (NMR) spectroscopy is a powerful tool for chemical structure elucidation, but for paramagnetic molecules it is substantially more complicated than in the diamagnetic case. Before the present work, the theory of NMR of ...

The results of a solid-state (11)B NMR study of a series of 10 boronic acids and boronic esters with aromatic substituents are reported. Boron-11 electric field gradient (EFG) and chemical shift (CS) tensors obtained from analyses of spectra acquired in magnetic fields of 9.4 and 21.1 T are demonstrated to be useful for gaining insight into the molecular and electronic structure about the boron...

The response of collisionless plasmas to an applied potential can differ from classic Debye shielding, and when the potential is rapidly applied ~‘‘instantaneous shielding’’!, the shielding can differ from when it is slowly applied ~‘‘adiabatic shielding’’!. Experiments demonstrate that when a test potential well is applied to a one-dimensional pure-electron plasma, instantaneous and adiabatic ...

a projective parameter of a geodesic as solution of certain ode is defined to be a parameter which is invariant under projective change of metric. using projective parameter and poincaré metric, an intrinsic projectively invariant pseudo-distance can be constructed. in the present work, solutions of the above ode are characterized with respect to the sign of parallel ricci tensor on a finsler s...