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Planar, 1D photonic crystals (1D-PCs) are stacks of alternating layers with different refractive indices, which can reflect specific wavelengths light through the formation a bandgap. Typical systems for 1D-PC fabrication possess relatively limited thermal and/or chemical stabilities and may require several steps producing patterned features. Additionally, enabling stimuli-responsive behaviors ...
Macro/mesoporous carbon monoliths with a graphitic framework were synthesized by carbonizing polymeric monoliths of poly(benzoxazine-co-resol). The overall synthesis process consists of the following steps: a) the preparation of polymeric monoliths by copolymerization of resorcinol and formaldehyde with a polyamine (tetraethylenepentamine), b) doping the polymer with a metallic salt of Fe, Ni o...
This study was conducted to evaluate the effects of bio-oil incorporation on properties of bio-oil-phenol formaldehyde (BPF) resol resins along with the optimization of petro-phenol substitution level. Crude bio-oil prepared from endocarp shells of Ziziphus mauritiana by direct solvolytic liquefaction (ethanol-water 1:1 wt./wt. at 300 °C) was used to partially substitute the petro-phenol (30% t...
Organosolv wheat straw lignin extracted using the CIMV process is a linear, low molecular weight, and natural phenolic oligomer. In this study, organosolv wheat straw lignin was tested as a substitute for 50% to 70% of the phenol in a phenol-formaldehyde-resol resin. The lignin was used without any chemical modification in a one-step synthesis reaction. Parameters such as reaction time and form...
Lipid-bilayer coated nanosized bimodal mesoporous carbon spheres for controlled release applications
Highly mesoporous nanosized carbon spheres (MCS) equipped with an active lipid bilayer demonstrate pronounced molecular release behavior, and excellent potential for drug delivery applications. We report a facile synthesis route for the creation of colloidal MCS with a bimodal pore size distribution, featuring a high BET surface area combined with high pore volume. Bimodal mesoporosity was achi...
Acacia mangium is a fast-growing dicotyledonous tree species and has become the dominating plantation in Malaysia. It was grown particularly as a raw material for veneer, pulp, and paper industries. The chemical properties test in this study showed that the A. mangium tree bark contains higher extractive content as compared to the wood portion (sapwood). Tannin extracts from A. mangium tree bar...
Porous carbon monoliths with defined multilength scale pore structures, a nitrogen-containing framework, and high mechanical strength were synthesized through a self-assembly of poly(benzoxazine-co-resol) and a carbonization process. Importantly, this synthesis can be easily scaled up to prepare carbon monoliths with identical pore structures. By controlling the reaction conditions, porous carb...
The purpose of this study is to develop a low-formaldehyde-emitting resin system for medium density fibreboards (MDF). A combination of polyamines with phenolic resins seems to be suitable for this purpose. To produce panels with such a resin system, polyethylenimine, and a phenolic resin were separately applied on fibres and subsequently made into boards in a thermal pressing process. It was d...
We demonstrate the preparation of rationally designed, multifunctional, monolithic and periodically ordered mesoporous core-shell nanocomposites with tunable structural characteristics. Three-dimensionally (3D) co-continuous gyroidal mesoporous polymer monoliths are fabricated from a solution-based triblock terpolymer-resol co-assembly and used as the functional templates for the fabrication of...
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