A Pd-catalyzed single-step C-H arylation of dioxythiophene derivatives bearing unprotected reactive functional groups (-OH, -COOH, -N3) in a phosphine-free manner has been developed. Various dioxythiopene-based oligoarenes with extended π-conjugation are obtained with good yields (up to 90%). These oligoarenes display suitable optical properties (absorption and emission maxima, quantum yields) ...

This paper presents electromagnetic energy absorption in the homogeneous and layered human body models due to body-worn UWB antennas, at frequencies of 3, 6 and 8 GHz. Typical small planar UWB antennas are used in this study: printed UWB disc monopole and UWB slot antenna. Distances of 2, 5 and 10 mm (reactive near-field region) between antennas and human body were chosen, approximating realist...

Visible-light triggered quinone trimethyl locks are reported as a general design for long-wavelength photoremovable protecting groups for alcohols and amines. Intramolecular photoreduction unmasks a reactive phenol that undergoes fast lactonization to release alcohols and amines. Model substrates are released in quantitative yield along with well-defined, colorless hydroquinone byproducts. Subs...

The absorption of radioactive cholesterol tended to be increased, and the catabolism of cholesterol detected by the decay of radioactive cholesterol in the serum after the intraperitoneal injection was delayed in ALR in comparison with normotensive WK rats. The reactive hypercholesterolemia in the ALR which had been selectively bred for a greater hypercholesterolemia was ascribed to the decreas...

Imaging scheme based on Acetone-OH simultaneous PLIF (Planer Laser-Induced Fluorescence) is applied for diagnostics of reactive zone over the premixed flames and the reactive zone imaging are demonstrated for turbulent premixed flame conditions. In the present study, visualization of reactive zone is brought by simultaneous measurement of unburned zone through acetone (seeded into the fuel flow...

Xanthine oxidase (XO), a key enzyme in purine metabolism, produces reactive oxygen species causing vascular injuries and chronic heart failure. Here, copper's ability to alter XO activity and structure was investigated in vitro after pre-incubation of the enzyme with increasing Cu(2+) concentrations for various periods of time. The enzymatic activity was measured by following XO-catalyzed xanth...

Immunofluorescent staining of Treponema pallidum was studied to clarify the effect of three factors on the results of the fluorescent treponemal antibody-absorption test: (i) heat inactivation of sera at 56 degrees C for 30 min before testing, (ii) use of multicircle slides, and (iii) tungsten illumination to visualize and assess unstained treponemes on reactive as well as nonreactive smears. I...

A complement-fixing, heart-reactive serum component that develops in dogs following experimental myocardial infarction was characterized with respect to its immunoglobulin nature and its subcellular membrane and organ specificities. The immunoglobulin nature of the heart-reactive serum factor was established by the following evidence: (1) the factor was not removed from the serum following abso...

A modified pH 1.0 liquid redox sulfur recovery (LRSR) process, based on reactive absorption of H(2)S((g)) in an acidic (pH 1.0) iron solution ([Fe(III)] = 9-8 g L(-1), [Fe(II)] = 1-2 g L(-1)) and electrochemical regeneration of the Fe(III)/Fe(II) catalyst couple, is introduced. Fe(II) was oxidized in a flow-through electrolytic cell by Cl(2(aq)) formed on a Ti/RuO(2) anode. pH 1.0 was applied t...