In this study, a new type of alumina-coated magnetite nanoparticles (Fe3O4/Al2O3 NPs) with sodium dodecyl sulfate1-(2-pyridylazo)-2-naphthol (SDS-PAN) as a new sorbent solid phase extraction (SPE) has been successfully synthesized and applied for preconcentration and separation of Pb (II). The metal was eluted with 3 mL HNO3 2 mol L directly and detected by flame atomic absorption spectrometry ...

Determination methods of halide ions (X(-) = F(-), Cl(-), Br(-) and I(-)) by electrospray ionization mass spectrometry (ESIMS) were developed, where negative ions of the ternary complexes of group-13 elements, nitrilotriacetic acid (NTA), and halides were measured. In particular, these halides were simultaneously determined by measuring [InX(nta)](-), and the limits of detection (LODs) were 1.1...

lead is quantitatively retained on 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-br-padap)-ammonium tetraphenylborate with microcrystalline naphthalene or by a column method in the ph range 4.0-6.0 from a large volume of aqueous solutions of various samples with preconcentration factor of 60. after filtration, the solid mass consisting of the lead complex and naphthalene was dissolved with 5...

A fiber optic sensor for monitoring mercuric (Hg2+) ions in the aqueous sample have been developed based on modified cladding. To fabricate a D-shaped sensing zone onto multimode optical lengthwise polishing was utilized using mechanical end and edge system. The produced region has dimensions of 10 mm × 125 μm 62 (l w h). 2 thin layer Al2O3 nanoparticles sensitized with 4-(2-pyridylazo)-resorci...

The capability of high-speed countercurrent chromatography (HSCCC) has been investigated for enrichment and determination of metal ions at trace levels. Separation of selected divalent metal ions was performed using a small coiled column. A hexane solution of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHPA) was employed as the stationary phase. Loaded divalent metal ions such as Ni, C...