the kinetics and mechanism of the reaction between benzaldehyde 1, malononitrile 2 and dimedone 3 in a mixture of ethanol and water as solvents in the presence of fructose as a biodegradable catalyst has been studied by the spectroscopic method (uv-vis spectrophotometry method). the influence of various parameters (temperature, solvent and concentration) was studied on the reaction by means of ...

Graphene, a new member of the carbon family, was used as an adsorbent due to its exceptional capability to remove Rhodamine B (RB) and Malachite Green (MG), two organic dyes, from aqueous solutions. Adsorption kinetics of RB and MG onto graphene and adsorption capacity of the adsorbent were studied. Also the effects of parameters, including pH, contact time, temperature, and adsorbent dosag...

Adsorption capacity of 4-chloro-2-nitrophenol (4C2NP) onto nano-Ti02 from aqueous solutions wasinvestigated in a batch system by considering the effects of various parameters like contact time, nano-TiO2 dosage, initial pH and initial 4C2NP concentration. Optimum conditions for 4C2NP adsorptionwere found to be initial pH z 2, nano-TiO2 closer- 0.01 g and equilibrium time 1 h. The adsorptionkine...

We studied different face velocity and carbon dioxide (CO2) initial concentration to examine the adsorption behavior of calcium oxide (CaO) impregnated activated carbon (AC) filter and also to discuss pseudo-first-order, pseudo-second-order and intra-particle diffusion three kinetic models. The experimental results show that saturation time and saturation capacity were decreased and increased w...

In this study adsorption of 1-chloro-4-nitrobenzene (CNB) from aqueous solutions onto multi-walled carbon nanotubes (MWCNTs) was surveyed. The effect of some key parameters such as pH (2-10), carbon nanotubes dosage (0.02-0.1 mg/250mL), CNB concentration (2- 16 mg/L), and temperature (20,30,40,50°C) were investigated. The results showed that, the variation of initial pH and CNB concentration ex...

In this study adsorption of 1-chloro-4-nitrobenzene (CNB) from aqueous solutions onto multi-walled carbon nanotubes (MWCNTs) was surveyed. The effect of some key parameters such as pH (2-10), carbon nanotubes dosage (0.02-0.1 mg/250mL), CNB concentration (2- 16 mg/L), and temperature (20,30,40,50°C) were investigated. The results showed that, the variation of initial pH and CNB concentration ex...

the removal of as(iii) ions from aqueous solutions has been investigated using silica ceramic under different experimental conditions of initial arsenite concentration, adsorbent dose, temperature and ph. better removal was obtained at temperature 25âºc and ph 7.5. the adsorption data have been explained in terms of langmuir and freundlich equations. the sorption kinetics was tested for the pse...

zinc ions are present in different types of industrial effluents, being responsible for environmental pollution. biosorption is a process in which solids of natural origin are employed for binding heavy metals. it is a promising alternative method to treat heavy metal wastes mainly because of high metal binding capacity. the effect of some important parameters on sorption capacity of cyanobacte...

Background: Water pollution is an important environmental problem, undoubtedly, the presence of toxic heavy metals forms the main source of water contamination. Sorption characteristics of polyurethane foams modified with bis (2-ethylhexyl)phosphoric acid (DEHPA) for the removal of zinc, lead and cadmium ions from contaminated solutions were investigated. Methods: Operating variables, such as ...