The trends in octahedral tilting Prussian blue analogues are reviewed as a function of various structural factors. link between and functionality is discussed.

Cesium radioactive isotopes (134Cs and 137Cs) are dangerous to human health due to their long half-life and high solubility in water. Nuclear experiments, wars, and nuclear plant accidents have been the main sources of Cs release into the environment. In recent years, several methods have been introduced for the elimination of Cs radioactive isotopes from contaminated wate...

Thin films of iron(W) hexacyanoferrate(I1) (Prussian Blue) were electrochemically deposited on interdigitated array (IDA) electrodes, yielding systems which can be considered as chemiresistors in sensing alkali metal ion concentrations in an adjacent electrolyte. This is due to the fact that the conductivity of the film being measured by a steady-state current on application of a voltage to the...

Hybrid films composed of reduced graphene oxide (RG-O) and Cu nanowires (NWs) were prepared. Compared to Cu NW films, the RG-O/Cu NW hybrid films have improved electrical conductivity, oxidation resistance, substrate adhesion, and stability in harsh environments. The RG-O/Cu NW films were used as transparent electrodes in Prussian blue (PB)-based electrochromic devices where they performed sign...

Synthesis strategies for highly condensed {Fe11} and {Fe16} pivalate clusters have been developed based on archetypal geometrically frustrated triangular {Fe3(μ3-O)} motifs that are interlinked via oxo, hydroxo, ethoxo, and carboxylate groups.

Dispersible, nearly isolated 6 nm nanoparticles of the CsNiCr(CN)6 Prussian blue analogue coated with polyvinylpyrrolidone (PVP) show superparamagnetic behaviour with a relatively high blocking temperature TB = 9 K.