Nanomaterial of Cu(3)(BTC)(2) (BTC = benzene tricarboxylic acid) incorporating Keggin heteropolyacid conveniently prepared at room temperature and recovered by freeze drying outperforms ultrastable Y zeolite in acid catalysed esterification reaction.

A double-blind cross-over study was performed to evaluate the inhibitory activity of silver zeolite (SZ) mouthrinse on plaque formation. Eleven dental students participated in this study. SZ mouthrinse was prepared by suspending SZ powder into phosphate-buffered saline (PBS) at a concentration of 3% (w/w). Type-A zeolite was used as a placebo. Before the experiment, the subjects were rendered p...

A double-blind cross-over study was performed to evaluate the inhibitory activity of silver zeolite (SZ) mouthrinse on plaque formation. Eleven dental students participated in this study. SZ mouthrinse was prepared by suspending SZ powder into phosphate-buffered saline (PBS) at a concentration of 3% (w/w). Type-A zeolite was used as a placebo. Before the experiment, the subjects were rendered p...

Zeolite Y nanosheets with a micro-meso-macroporous structure were synthesized, and applied in the assembly of a Pd catalyst (Pd/NS-Y) for direct vinylation of thiophenes with high activity and selectivity, as compared to Pd(OAc)2, Pd(NO3)2, and Pd(PPh3)4 catalysts. This feature should be assigned to the highly dispersed Pd(δ+) (δ < 2) species in Pd/NS-Y, which are more active than Pd(2+).

In this study, beta nanozeolite, ultra-stable Y zeolite (USY) and amorphous silica-alumina (ASA) were synthesized. These compounds were used as the support of hydrocracking catalyst. Ni-Mo/beta zeolite-ASA and Ni-Mo/USY zeolite-ASA catalysts were prepared by the impregnation method. The samples were characterized with X-Ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM)...

Time-resolved near-IR phosphorescence spectroscopy was employed to determine the lifetime of singlet oxygen in Y-zeolites and porous silica and it was found to depend strongly on the alumina content of the zeolite.

Ru(III)-exchanged FAU-Y zeolite was used as an efficient reusable heterogeneous catalyst for preparation of oxindoles from condensation reaction of indoles with isatins under very mild reaction conditions.

By using laser ablation of the mixtures of a transition metal (M: Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Pd, Ag) plus lead, M/Pb binary cluster anions were observed except for Zn, and the number of transition metal atoms contained in the binary clusters is at most 4. This behavior is different from that reported previously for M/Ge binary clusters. The experiments indicate that it is also very difficu...

Cu-exchanged Y zeolite was investigated in order to determine the location of the copper cations relative to the zeolite framework and to determine which Cu cations are active for the oxidative carbonylation of methanol to dimethyl carbonate (DMC). Cu-Y zeolite was prepared by vapor-phase exchange of H-Y with CuCl. The oxidation state, local coordination, and bond distances of Al and Cu were de...