the reaction of p-diketones 1 with phenyl hydrazine afforded 5-aryl-3-(1- methyl-5-nitro-2-imidazoly1)-1-phenylpyrazole (2) and 3-aryl-5-(1-methyl-5- nitro-2-imidazoly1) -1-phenylpyrazole (3). the reaction of diketones (1) with urea in the presence of p-toluenesulfonic acid gave 4-(or 6-)aryl-6-(or 4-)(1-methyl- 5-nitro-2-imidazolyl)-1-(lh)pyrimidones (4). the structures of all compounds were c...

A facile and efficient synthetic route to polyhydroquinolines has been developed via four-component condensation reactions of aldehydes, dimedone, ethyl acetoacetate and ammonium acetate in the presence of p-toluenesulfonic acid (p-TSA) catalyst in ethanol at ambient temperature through Hantzsch reaction. Simple work-up procedure, environmentally friendly, inexpensive and non-toxic catalyst, sh...

1566-7367/$ see front matter Crown Copyright 2 doi:10.1016/j.catcom.2010.01.010 * Corresponding authors. Tel./fax: +86 (21)6425382 E-mail addresses: [email protected] (J. Ren), w Wang). A novel carbon-based solid-acid catalyst was simply prepared for the first time by the thermal treatment of p-toluenesulfonic acid (TsOH) with D-glucose at 180 C in a sealed autoclave and it was proved to ha...

For environmental reasons, a new class of environmentally acceptable and renewable biolubricant based on vegetable oils is available. In this study, oxirane ring opening reaction of monoepoxide linoleic acid (MEOA) was done by nucleophilic addition of oleic acid (OA) with using p-toluene sulfonic acid (PTSA) as a catalyst for synthesis of 9(12)-hydroxy-10(13)-oleoxy-12(9)-octadecanoic acid (HYO...

In this study an improved process for the production of 5-Methyl-1,2,4-triazolo(3,4-b) benzothiazole fungicide (IV) is described. Firstly, (2-methylphenyl) thiourea (I), 2-amino- 4-methylbenzothiazole (II) and 2-hydrazino-4-methylbenzothiazole (III) as intermediates consequently were prepared. Then IV is synthesized by the reaction of III with formic acid in the presence of p-toluenesulfonic ac...

This study aims to examine the operating pressure effect on manufacture of biodiesel from Palm Kernel Fatty Acid Distillate (PKFAD) by using para-Toluene Sulfonic (PTSA) catalyst. The pressures studied are vacuum 70 kPa, 80 90 and 100 which varied with PTSA concentrations 5%, 10%, 15%, 20%, 25%, molar ratios methanol PKFAD 5:1, 6:1, 7:1, 8:1, 9:1, 10:1. Biodiesel production is carried out react...

The reaction of P-diketones 1 with phenyl hydrazine afforded 5-aryl-3-(1- methyl-5-nitro-2-imidazoly1)-1-phenylpyrazole (2) and 3-aryl-5-(1-methyl-5- nitro-2-imidazoly1) -1-phenylpyrazole (3). The reaction of diketones (1) with urea in the presence of p-toluenesulfonic acid gave 4-(or 6-)aryl-6-(or 4-)(1-methyl- 5-nitro-2-imidazolyl)-1-(lH)pyrimidones (4). The structures of all compounds w...

Complex permittivity of conducting polypyrrole (PPy)-coated Nylon-Lycra textiles is measured using a free space transmission measurement technique over the frequency range of 1-18 GHz. The aging of microwave dielectric properties and reflection, transmission and absorption for a period of 18 months is demonstrated. PPy-coated fabrics are shown to be lossy over the full frequency range. The leve...