The title compound, [Cu(C(12)H(8)N(2))(2)](2)[W(6)O(19)], consists of two [Cu(phen)(2)](+) cations (phen = 1,10-phenanthroline) and one typical [W(6)O(19)](2-) isopolyanion. The Cu(I) atom is coordinated by four N atoms from two bidentate chelating phen ligands in a distorted tetra-hedral geometry. The hexa-tungstate anion, lying on an inversion center and possessing the well known Lindqvist st...

In the title complex, [La(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by eight O atoms from two 2-oxido-pyridinium-3-carboxyl-ate ligands, two oxalate ligands and two water mol-ecules in a distorted bicapped square-anti-prismatic geometry. The carboxyl-ate groups link adjacent La(III) ions, forming two-dimensional layers that are further linked by N-H⋯O and O-H⋯O hydr...

The hydroxido-bridged dinuclear ruthenium complex 4, which is supported by Tp ligands, has been prepared from protonation of the oxido-bridged dinuclear ruthenium complex 3. Additional protonation of 4, affording the aqua-bridged dinuclear ruthenium complex 5 in situ, and subsequent treatment with NO gave rise to the dicationic dinitrosyl complex 2. These indicate completion of the NO reduction...

The solid-state structure of the new compound μ-oxido-bis[dichloridotris(tetrahydrofuran-κ O )titanium(III)], [Ti 2 Cl 4 O(C H 8 O) 6 ], at 150 K has been determined. crystal monoclinic ( C 2/ c ) symmetry and complex features about bridging atom. Positional disorder is evident in one three tetrahydrofuran environments. A post-Hartree–Fock computational analysis indicates that nearly degenerate...

Two oxidovanadium(V) complexes, [VOL1L] (1) and [VOL2L] (2) (L = ethyl maltolate), derived from the aroylhydrazones 4-bromo-N’-(2-hydroxy-5-methylbenzylidene)benzohydrazide (H2L1) N’-(3,5-dibromo-2-hydroxybenzylidene)- 4-methoxybenzohydrazide (H2L2), respectively, have been synthesized characterized by elemental analysis, infrared electronic spectroscopy. Structures of complexes were further co...

The title compound, [Mo(4)(C(16)H(20))(2)O(8)]·6H(2)O, is a centrosymmetric ansa-molybdocene complex in which two dinuclear [C(2)Me(4)(η(5)-C(5)H(4))(2)]Mo(μ(2)-O)(2)MoO(2) units dimerize by forming two μ(3)-O bridges between three Mo atoms. The ansa-molybdocene [C(2)Me(4)(η(5)-C(5)H(4))(2)]Mo unit has a typical bent-sandwich metallocene structure with an inter-ring angle of 127.98 (8)°. The Mo...

The crystal structures of paramagnetic N-o-oxido-benzimido-meso-tetraphenylporphyrinato (-kappa(4),N(1),N(2),N(3),N(5),kappaO(2))cobalt(III) [Co(N-NCO(o-O)C(6)H(4)-tpp); 2] (S = 1) and diamagnetic N-o-oxido-benzimido-meso-tetraphenylporphyrinato (-kappa(4),N(1),N(2),N(3),N(5),kappaO(2)) gallium(III) chloroform.methanol solvate [Ga(N-NCO(o-O)C(6)H(4)-tpp).0.5CHCl(3).MeOH; 3.0.5CHCl(3).MeOH] (S =...

Crown-ether like interaction of two neutral [Cu2(μ-OH)(μ-L(1))] (H3L(1) = 2-(2'-hydroxyphenyl)-1,3-bis[4-(2-hydroxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine) fragments, around a central Na(+) cation as self-assembly template, led to the formation of [Na{Cu2(μ-OH)(μ-L(1))}2]ClO4 (1). Di-tert-butyl group substituted H3L(2) {2-(3,5-di-tert-butyl-2-hydroxyphenyl)-1,3-bis[4-(3,5-di-tert-butyl-2-hyd...

BACKGROUND We compared the proteome profile of peritoneal effluents obtained with icodextrin (Ico) or glucose (Glu) in paediatric patients and defined the oxido-redox status of proteins. METHODS Sixteen patients underwent two 14-h daytime dwells performed on subsequent days with 7.5% Ico and 3.86% Glu solutions. Protein composition was analysed by two-dimensional electrophoresis and mass spec...