in this work, spherical pt nanometer-scale particles supported on the poly (m-toluidine)/triton x-100 film modified carbon nanotube paste electrode (pt/pmt (tx-100)/mcntpe) was used as a potent catalyst for electrooxidation of formaldehyde (hcho) in both 0.5 m h2so4 and 0.1 m naoh solutions. the obtained results showed that utilization of tx-100 as an additive during the electropolymerization p...

the electrochemical oxidation of sulfamethazine (smz) has been studied at a multi-walled carbon nanotubes modified glassy carbon electrode (mwcnt-gce) by cyclic voltammetry. this modified electrode (mwcnt-gce) exhibited excellent electrocatalytic behavior toward the oxidation of smz as evidenced by the enhancement of the oxidation peak current and the shift in the anodic potential to less posit...

In this study, the effects of mechanical milling and YSZ reinforcing on oxidation behavior of CoNiCrAlY coatings were investigated. Various amounts of YSZ particles (0%, 5%, 10% and 15 wt.%) were mixed with commercial CoNiCrAlY powder and milled for 24 hrs. Then, the mechanically milled and commercial powders were deposited on Inconel 617 substrate using High Velocity Oxygen-Fuel (HVOF) process...

in the present work, the electrooxidation of formic acid and formaldehyde; potentially important fuels for future fuel cells, was investigated on the fe3o4@pt core-shell nanoparticles/carbon-ceramic electrode (fe3o4@pt/cce). the fe3o4@pt nanoparticles were prepared via a simple and fast chemical method and their surface morphology, nanostructure properties, chemical composition, crystal phase, ...

the perovskite-structured la2cuo4 nanoparticles (lco nps) have been synthesized via an ultrasonic-assisted co-precipitation route using octanoic acidas organic surfactant, and the phase composition, morphology, lattice parameters and size of nanoparticles  are characterized through fourier transform infrared spectroscopy (ft-ir), x-ray diffraction (xrd), scanning electron microscopy (sem) and t...

Oxidation behavior of AZ91D magnesium alloy with 3YSZ coating and aluminum interlayer was studied in air at 250 °C using electrochemical impedance spectroscopy EIS, scanning electron microscopy SEM, and X-ray diffraction XRD. The oxidation process was carried out in various duration times from 1 to 10 h. A three-electrode electrochemical cell was employed for all the EIS measurements. Also, to ...

We report on the oxidation behavior of AlN/CrN multilayers at 900 °C, deposited by radio frequency magnetron sputtering. It is shown that oxidation in this system is controlled by diffusion of Cr towards the surface and formation of Cr2O3. Cr diffusion is found to mainly occur along grain boundaries. Thus, coherent cubic AlN/CrN multilayer regions with coarse columnar grain structures are found...

A unique magnetic electroswitching behavior has been observed in an oxamato-based permethylated dicopper(II) paracyclophane; upon reversible one-electron oxidation of the double tetramethyl-substituted p-phenylenediamidate bridging skeleton, the spin alignment of the two Cu(II) ions (S(Cu) = ½) changes from antiparallel (OFF) to parallel (ON) in the resulting dicopper(II) π-radical cation species.

The fact that oxidation, as one of the main routes of phase I metabolism of drugs, follows by conjugation reactions, and also formation of nitrenium ion as one of the clozapine oxidation products, directed us to investigate the oxidation of clozapine (CLZ) in the presence of nucleophile. The oxidation of clozapine (CLZ) has been studied on a glassy carbon electrode in the absence and presence o...

In this study, the effect of surface morphologies on the isothermal oxidation behavior of MCrAlY coatings fabricated by high-velocity oxyfuel (HVOF) processes was investigated. To do so, free standing coatings with as-sprayed and polished surfaces were isothermally oxidized at 1050°C. The thickness of the bond coat was approximately 380μm. The Ra of the as-sprayed and polished surfaces were 6.4...