background and objectives: the mobility, bioavailability and environmental fate of heavy metal ions in soil are controlled by sorption onto soil minerals and solid organic matter. the sorption is strongly affected by the presence of various low-molecular-weight organic acids. the main objective of this study was to investigate the effects of oxalic acid on sorption of cd on clay fraction of a s...

Oxalic acid is a prevalent fungal metabolite with versatile roles in growth and nutrition, including degradation of plant biomass. However, the toxicity of oxalic acid makes regulation of its intra- and extracellular concentration crucial. To increase the knowledge of fungal oxalate metabolism, a transcriptional level study on oxalate-catabolising genes was performed with an effective lignin-de...

Rumen microbial degradation is an important route for detoxification of secondary plant compounds encountered in the diets of free-grazing ruminants. Exposure to diets containing particular secondary plant compounds can lead to increased rates of secondary compound degradation in the rumen. An experiment was conducted to determine whether rumen adaptation to oxalic acid would influence the diet...

The heterogeneous ice nucleation potential of airborne oxalic acid dihydrate and sodium oxalate particles in the deposition and condensation mode has been investigated by controlled expansion cooling cycles in the AIDA aerosol and cloud chamber of the Karlsruhe Institute of Technology at temperatures between 244 and 228 K. Previous laboratory studies have highlighted the particular role of oxal...

Background: We conducted an assessment of knowledge about blood borne pathogens (BBP) and use of universal precautions at first level care facilities (FLCF) in two districts of Pakistan. Methods: We conducted a cross-sectional survey and selected three different types of FLCFs ; public, general practitioners and unqualified practitioners through stratified random sampling technique. At each fac...

Hydrothermal pyrolysis experiments were performed to assess condensation (dehydration) reactions to amide, ester, and nitrile functionalities from lipid precursors. Beside product formation, organic compound alteration and stability were also evaluated. Mixtures of nonadecanoic acid, hexadecanedioic acid, or hexadecanamide with water, ammonium bicarbonate, and oxalic acid were heated at 300 deg...

Single crystal X-ray diffraction of oxalic acid dihydrate H(2)C(2)O(4).2H(2)O (1), at pressures up to 5.3 GPa, shows significant changes in the molecular geometries, probably accompanied by a proton migration from H(2)C(2)O(4) to H(2)O and formation of ionic species, as predicted by periodic DFT calculations.

Metabolic conversion of l-galactono-1, 4-lactone and l-ascorbic acid to (+)-tartaric acid and oxalic acid has been studied in Pelargonium crispum, cv. Prince Rupert. Experiments with specifically labeled substrates suggest a path of conversion involving cleavage of l-ascorbic acid, or a metabolic product of l-ascorbic acid, between C(2) and C(3), such that oxalic acid arises from the two carbon...

A simple, automated colorimetric method for determining oxalic acid in plant material is based on the quantitative reduction in colour of a zirconium/3,4-dihydroxyazobenzene-2'-carboxylic.acid complex by microgram quantities of oxaIic acid. I t is suitable for use over a wide range of oxalic acid concentrations. Interference from phosphate, sulphate, citric acid and malic acid was encountered b...