The form or speciation of a metal in natural waters can change its kinetic and thermodynamic properties. For example, Cu(II) in the free ionic form is toxic to phytoplankton, while copper complexed to organic ligands is not toxic. The form of a metal in solution can also change its solubility. For example, Fe(II) is soluble in aqueous solutions while Fe(III) is nearly insoluble. Natural organic...

The electronic properties of semiconducting inorganic lead sulfide (PbS) nanocrystals (NCs) and organic linker molecules are dependent on the size NCs as well used ligands. Here, we demonstrate that a weakly binding ligand can be successfully attached to PbS form coupled organic–inorganic nanostructure (COIN) by mixing with strong partner. We use zinc β-tetraaminophthalocyanine (Zn4APc) in comb...

In the oligotrophic North Atlantic and North Pacific, ultrafiltration studies show that concentrations of soluble iron and soluble iron-binding organic ligands are much lower than previously presumed "dissolved" concentrations, which were operationally defined as that passing through a 0.4-micrometer pore filter. Our studies indicate that substantial portions of the previously presumed "dissolv...

Colloidal-quantum-dot (CQD) optoelectronics offer a compelling combination of solution processing and spectral tunability through quantum size effects. So far, CQD solar cells have relied on the use of organic ligands to passivate the surface of the semiconductor nanoparticles. Although inorganic metal chalcogenide ligands have led to record electronic transport parameters in CQD films, no phot...

Nanoindentation measurements of electrophoretically deposited films of colloidal CdSe nanocrystals, capped by organic ligands, show the films have an elastic stiffness modulus of approximately 10 GPa and exhibit viscoplasticity. This mechanical response suggests polymeric features that are attributable to the ligands. After particle cross-linking and partial ligand removal, the films exhibit mo...

Biphenols are important structure motifs for ligand systems in organic catalysis and are therefore included in the category of so-called "privileged ligands". We have developed a new synthetic pathway to construct these structures by the use of selenium dioxide, a stable, powerful, and commercially available oxidizer. Our new, and easy to perform protocol gives rise to biphenols and diaryl sele...

Inorganic nanoparticles, stabilized by a passivating layer of organic molecules, form a versatile class of nanostructured materials with potential applications in material chemistry, nanoscale physics, nanomedicine and structural biology. While the structure of the nanoparticle core is often known to atomic precision, gaining precise structural and dynamical information on the organic layer pos...

Morin has often been used to stain and localise Aluminium in plant tissues. But formation of the morin-Al complex is strongly influenced by the binding stage of Al. As Eticha et al. (2005) pointed out morin is not able to stain Al, which is bound to cell-wall pectin. Lian et al. (2003) assumed also that the morin-Al complex is weak in comparison with other ligands such as oxalate. With regard t...

Organic compounds contained in radioactive waste can be classified into different categories. The ability of organic compounds to form stable complexes with metallic cations is widely recognized. The effect of Low Molecular Weight (LMW) organic compounds present in the wastes, or produced via their degradation on the mobilization of radionuclides under repository conditions must be assessed. Fo...

Metal−organic frameworks (MOFs), a class of porous materials, are of particular interest in gas storage and separation applications due largely to their high internal surface areas and tunable structures. MOF-5 is perhaps the archetypal MOF; in particular, many isoreticular analogues of MOF-5 have been synthesized, comprising alternative dicarboxylic acid ligands. In this contribution we introd...