Quantitative mapping of metal ions freely diffusing in solution is important across a diverse range of disciplines and is particularly significant for dissolution processes in batteries, metal corrosion, and electroplating/polishing of manufactured components. However, most current techniques are invasive, requiring sample extraction, insertion of an electrode, application of an electric potent...

The catalytic oxidation of CO molecule on a thermodynamically stable Cu4 cluster doped MoS2 monolayer is investigated by density functional theory (DFT) where the reaction proceeds in a new formation order of COOOCO* (O2* + 2CO* → COOOCO*), OCO* (COOOCO* → CO2 + OCO*), and CO2 (OCO* → CO2) desorption with the corresponding reaction barrier values of 0.220 eV, 0.370 eV and 0.119 eV, respectively...

Abstract: This research examines the performance of strengthened non-uniformly corroded reinforced self-consolidating concrete (SCC) members. This paper focuses on three aspects of concrete including corrosion, concrete cover loss, and repair technique. Up to a 50% corrosion level is considered in this study. Corrosion was experimentally induced and was simulated in other cases. Twenty-six rein...

The stability of an electrodeposited nanocrystalline Ni-based alloy coating in a H₂S/CO₂ environment was investigated by electrochemical measurements, weight loss method, and surface characterization. The results showed that both the cathodic and anodic processes of the Ni-based alloy coating were simultaneously suppressed, displaying a dramatic decrease of the corrosion current density. The co...

The successful development of Li-O2 battery technology depends on resolving the issue of cathode corrosion by the discharge product (Li2O2) and/or by the intermediates (LiO2) generated during cell cycling. As an important step toward this goal, we report for the first time the nanoporous Ni with a nanoengineered AuNi alloy surface directly attached to Ni foam as a new all-metal cathode system. ...

y-tial intermetallic alloy have a good potential for use as biomaterial, due to its good corrosion resistance. in this paper, two fundamental electrochemical techniques namely electrochemical impedance spectroscopy and potentiodynamic anodic polarization were used to evaluate the corrosion performance of g-tial in ringer's solution. surface modification treatments were employed with the pu...

A mini-flowloop was developed to study CO2 corrosion and corrosion/erosion interactions, and to assess the effectiveness of inhibitors under conditions that simulate multi-phase pipelines. The miniflowloop was used to study the effect of testing time, steel chemistry, velocity, temperature, fluid chemistry, sand and inhibitors on corrosion rates. The measured corrosion rates in inhibited and un...

Five non-precious Ni-Co based alloys were analyzed with respect to their corrosion behaviour. The correlation between the amount of the elements Cr, Mo, V and the corrosion behaviour, expressed by the PREN (pitting resistance equivalent number) index in the case of the allied steels, was extended for Ni-Cr and Co-Cr dental alloys characterization. Open circuit potential, corrosion current densi...

In this study, micro-oxygen was integrated into a rusty scrap iron (RSI)-loaded anaerobic digester. Under an optimal RSI dosage of 20 g/L, increasing O2 levels were added stepwise in seven stages in a semi-continuous experiment. Results showed the average methane yield was 306 mL/g COD (chemical oxygen demand), and the hydrogen sulphide (H2S) concentration was 1933 ppmv with RSI addition. O2 ad...